caesium dioxosulphatovanadate(V) | 84936-94-7

• 英文名称: caesium dioxosulphatovanadate(V)
• CAS: 84936-94-7
• 化学式: Cs*O₂V*O₄S
• 分子量: 311.909
• InChiKey: BXRISEYDMBLBDW-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  水 、 caesium dioxosulphatovanadate(V) 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Phase ratios in the M2O-V2O5-SO3 (M = Rb, Cs) systems and the properties of the compounds formed in these systems

  摘要：

  Powder X-ray diffraction and microscopy have been used to study phase ratios of the M2O-V2O5-SO3 (M = Rb, Cs) systems, which model the active component of rubidium-vanadium and cesium-vanadium catalysts for sulfuric acid production at high sulfur dioxide conversions. We have stated that each system forms four compounds: M3VO2(SO4)(2), MVO2SO4, M4V2O3(SO4)(4), and MVO(SO4)(2). The thermal properties of these compounds and their interaction with water vapor saturated at room temperature have been studied. The unit cell parameters have been determined for the compounds MVO2SO4 (M = K, Rb), MVO(SO4)(2), and M[VO2(SO4)(H2O)(2)] center dot H2O (M = Rb, Tl). The reciprocal transformations of the components and phases of the M2O-V2O5-SO3 systems match the Lux-Flood ideas of the acid-base properties of oxide compounds.

  DOI：

  10.1134/s0036023607030205
• 作为产物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 caesium dioxosulphatovanadate(V)
  参考文献：
  名称：

  Phase ratios in the M2O-V2O5-SO3 (M = Rb, Cs) systems and the properties of the compounds formed in these systems

  摘要：

  Powder X-ray diffraction and microscopy have been used to study phase ratios of the M2O-V2O5-SO3 (M = Rb, Cs) systems, which model the active component of rubidium-vanadium and cesium-vanadium catalysts for sulfuric acid production at high sulfur dioxide conversions. We have stated that each system forms four compounds: M3VO2(SO4)(2), MVO2SO4, M4V2O3(SO4)(4), and MVO(SO4)(2). The thermal properties of these compounds and their interaction with water vapor saturated at room temperature have been studied. The unit cell parameters have been determined for the compounds MVO2SO4 (M = K, Rb), MVO(SO4)(2), and M[VO2(SO4)(H2O)(2)] center dot H2O (M = Rb, Tl). The reciprocal transformations of the components and phases of the M2O-V2O5-SO3 systems match the Lux-Flood ideas of the acid-base properties of oxide compounds.

  DOI：

  10.1134/s0036023607030205

文献信息

• Synthesis, structure, and properties of M3VO2(SO4)2 (M = Rb, Cs)
  作者：V. N. Krasil’nikov、A. P. Tyutyunnik、V. G. Zubkov、I. F. Berger、L. A. Perelyaeva、I. V. Baklanova

  DOI：10.1134/s0036023610090019

  日期：2010.9

  Vanadium(V) complexes of general composition M3VO2(SO4)(2) (M = Rb, Cs) were synthesized by a solid-state route. The individuality of the synthesized compounds was proved by X-ray and neutron diffraction, vibrational spectroscopy, and microscopic analysis. The X-ray diffraction patterns of M3VO2(SO4)(2) were indexed to fit the monoclinic system (space group P2/c, Z = 4) with the following unit cell parameters: a = 11.6487(2) angstrom, b = 8.4469(2) angstrom, c = 12.1110(2) angstrom, beta = 109.483(1)degrees, V = 1123.43 angstrom(3) (Rb); a = 12.0546(3) angstrom, b = 8.7706(2) angstrom, c = 12.6496(3) angstrom, beta = 109.843(2)degrees, V = 1257.99 angstrom(3) (Cs). In the crystal structure of M3VO2(SO4)(2), [VO2(SO4)(2)](3-) complex anions can be discerned in which the vanadium atom is surrounded by five oxygen atoms: two oxygen atoms form short terminal V-O bonds, and three oxygen atoms are from the two sulfato groups, one of which acts as a monodentate ligand and the other acts as a bidentate chelating ligand.
• Krasil'nikov, V. N.; Glazyrin, M. P.; Ivakin, A. A., Russian Journal of Inorganic Chemistry, 1984, vol. 29, p. 53 - 55
  作者：Krasil'nikov, V. N.、Glazyrin, M. P.、Ivakin, A. A.

  DOI：——

  日期：——
• Crystal Structure and Spectroscopic Properties of CsVO₂SO₄
  作者：S. B. Rasmussen、S. Boghosian、K. Nielsen、K. M. Eriksen、R. Fehrmann

  DOI：10.1021/ic030314y

  日期：2004.6.1

  Dark crystals of the V(V) compound CSVO2SO4, Suitable for X-ray investigations have been obtained from the catalytically important Cs2S2O7-V2O5 system. By cooling of the mixture with the composition X-V2O5 = 0.5, some crystals were obtained in the otherwise glassy sample, The compound crystallizes in the orthorhombic space group Pbca with a = 6.6688(13) Angstrom, b = 10.048(2) Angstrom, and c = 17.680(4) Angstrom at 20 degreesC and Z = 8. It contains a coordination sphere with a short V-O bond of 1.595(2) Angstrom and trans to this the closest VO distance at 3.4 Angstrom and four equatorial V-O bonds in the range 1.725(1)-1.984(2) Angstrom. The deformation of the VO6 octahedron is thus much more pronounced compared to other known oxo sulfato V(V) compounds, and the coordination polyhedron of V(V) should be regarded as a tetragonal pyramid with the vanadium atom in the center. Each VO2+ group is coordinated to the neighboring groups by oxygen and sulfate double bridges in a zigzag structure where two sulfate oxygens virtually remain uncoordinated-one is found at the very long nonbonding V-O distance from the neighboring chain. This is the first time that we find pentacoordination of vanadium in the 12 different V(III), V(IV), and V(V) compounds examined so far. The FTIR and Raman spectra of the compound are in agreement with the simple formula unit of the investigated compound.