[PtOs3(CO)11(Pt-Bu3)2(Ph)(μ3-SnPh)] | 940938-85-2

• 英文名称: [PtOs3(CO)11(Pt-Bu3)2(Ph)(μ3-SnPh)]
• CAS: 940938-85-2
• 化学式: C₄₇H₆₄O₁₁Os₃P₂PtSn
• 分子量: 1751.36
• InChiKey: WLPKHUZEDIXWDI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Pt2Os3(CO)12(Pt-Bu3)2(μ2-Ph)(μ3-SnPh)] 在 P(t-Bu)3 作用下， 以 二氯甲烷 为溶剂， 以30%的产率得到[PtOs3(CO)11(Pt-Bu3)2(Ph)(μ3-SnPh)]
  参考文献：
  名称：

  Addition of Pt(PBu^t₃) to Osmium−Tin Cluster Complexes

  摘要：

  The reactions of the osmium-tin cluster complexes Os-3(CO)(12)(mu(3)-SnPh)Ph, 9, and Os-4(CO)(16)(mu(4)-Sn), 10, with Pt(PBu3t)(2) have been investigated. Two products, PtOs3(CO)(12)(Ph)(PBu3t)(mu(3)-SnPh), 11, and Pt2Os3(CO)(12)(mu(2)-Ph)(PBu3t)(2)(mu(3)-SnPh), 12, were obtained from the reaction of 9 with Pt(PBu3t)(2). These are mono- and bis-Pt(PBu3t) adducts of 9 formed by the addition of a Pt(PBu3t) group to the Os-Os bond in 11 and the Os-Os bond and Os-C bond to the sigma-bonded phenyl group in 12. A PBu3t derivative of 11, Os-2(CO)(8)(mu(3)-SnPh)Os(CO)(3)(PBu3t)Ph, 13, was obtained by treating 12 with PBu3t. The reaction of 10 with Pt(PBu3t)(2) provided the bis-Pt(PBu3t) adduct Os-4(CO)(16)[Pt(PBu3t)](2)(mu(4)-Sn), 14, that was formed by the addition of a Pt(PBu3t) group across the Os-Os bond of both Os-2(CO)(8) groups in 10. All four new compounds 11-14 were characterized by single-crystal X-ray diffraction analysis.

  DOI：

  10.1021/ic070261a