tetrahydroborato(tetrahydrofuran)(tetramethyl(n-propyl)cyclopentadienyl)samarium(III) | 1020152-56-0

• 英文名称: tetrahydroborato(tetrahydrofuran)(tetramethyl(n-propyl)cyclopentadienyl)samarium(III)
• CAS: 1020152-56-0
• 化学式: C₂₈H₅₀BOSm
• 分子量: 563.875
• InChiKey: SKLUJADYOGJXIQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Sm(BH₄)₃(THF)₃ 、 KC5Me4nPr 以 甲苯 为溶剂， 以68%的产率得到tetrahydroborato(tetrahydrofuran)(tetramethyl(n-propyl)cyclopentadienyl)samarium(III)
  参考文献：
  名称：

  Structural diversity in the borohydrido lanthanides series: First isolation and X-ray crystal structure of ionic

  摘要：

  The reaction of Sm(BH4)(3) (THF)(3) with a half equivalent of KCp*' (Cp*' = (C5Me4Pr)-Pr-n) affords a compound comprising one Cp*' ligand and three THF molecules per two Sm atoms, [Cp*'Sm-2(BH4)(5)(THF)(3)], according to analytical data. Crystals of penta-THF adduct 1, showing the same H-1 NMR spectrum except for the quantity of THF, could be isolated from a solution of half-samarocene Cp*'Sm(BH4)(2)(THF) (2). X-ray structure determination of 1 revealed an ionic compound [Sm(BH4)(2)(THF)(5)](+)[Cp*'Sm(BH4)(3)](-) with two discrete mononuclear Sm polyhedrons. The expected neutral samarocene Cp-2*'Sm(BH4)(THF)(3) could be obtained from the reaction of Sm (BH4)(3) (THF)(3) with two equivalents of KCp*'. X-ray structure analysis showed that 3 is a monomeric complex bearing a terminal borohydride ligand. All BH4- ligands in 1 and 3 exhibit an eta(3)-H3BH bonding mode. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.03.005