(2,6-(2,4,6-Me3C6H2)C6H3PH2)RuCl2(p-cymene) | 1179913-50-8

• 英文名称: (2,6-(2,4,6-Me3C6H2)C6H3PH2)RuCl2(p-cymene)
• CAS: 1179913-50-8
• 化学式: C₃₄H₄₁Cl₂PRu
• 分子量: 652.649
• InChiKey: INFNDSYTSYWZIM-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  (2,6-(2,4,6-Me3C6H2)C6H3PH2)RuCl2(p-cymene) 以 苯 为溶剂， 以47%的产率得到Cl2RuP(H2)C6H3-2-η6-2,4,6-Me3C6H2-6-2,4,6-Me3C6H2
  参考文献：
  名称：

  m-Terphenylphosphines: Synthesis, structures and coordination properties

  摘要：

  A series of m-terphenylphosphines TerphPCl(2), TerphPH(2) and TerphPMe(2) (Terph = 2,6-Mes(2)C(6)H(3)-, 2,6-(4-t-BuC6H4)(2)C6H3-, 2,6-(3,5-Me2C6H3)(2)C6H3-, 2,6-(2,6-Et2C6H3)(2)C6H3-, and 2,6-(2,6-i-Pr2C6H3)(2)C6H3-; Mes = 2,4,6-Me3C6H2-) was prepared and fully characterized. The structural investigation by X-ray crystallography and density functional theory revealed significant distortions in the environment of the ipso carbon and phosphorus centers. These can be traced back to steric interactions and repulsions of the chlorine and methyl substituents on phosphorus with one of the flanking arenes of the m-terphenyl substituents. The primary phosphine 2,6-Mes(2)C(6)H(3)PH(2), 6, and the dimethylphosphine 2,6-(3,5-Me2C6H3)(2) C6H3PMe2, 9, readily form complexes with the Cl2Ru(p-cymene) complex fragment, whereas the larger phosphine 2,6-Mes(2)C(6)H(3)PMe(2), 8, does not. Heating of the complexes TerphPR(2)Ru(Cl-2)(p-cymene) 11 and 12 and the mixture of 8 and {(p-cymene)RuCl2}(2) lead to expulsion of the p-cymene ligand and intramolecular eta(6) coordination of one of the flanking arene rings to the ruthenium center to afford the complexes Cl2RuP(H-2)C6H3-2-eta(6)-Mes-6-Mes, 13, Cl2RuP(Me-2)C6H3-2-eta(6)-Mes-6-Mes, 14, and Cl2RuP(H-2)C6H3-2-eta(6)-(3,5-Me2C6H3)-6-(3,5-Me2C6H3), 15. All complexes were characterized by NMR spectroscopy and complexes 14 and 15 also by X-ray crystallography. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.03.034
• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 2,6-dimesitylphenylphosphine 以 甲苯 为溶剂， 以85%的产率得到(2,6-(2,4,6-Me3C6H2)C6H3PH2)RuCl2(p-cymene)
  参考文献：
  名称：

  m-Terphenylphosphines: Synthesis, structures and coordination properties

  摘要：

  A series of m-terphenylphosphines TerphPCl(2), TerphPH(2) and TerphPMe(2) (Terph = 2,6-Mes(2)C(6)H(3)-, 2,6-(4-t-BuC6H4)(2)C6H3-, 2,6-(3,5-Me2C6H3)(2)C6H3-, 2,6-(2,6-Et2C6H3)(2)C6H3-, and 2,6-(2,6-i-Pr2C6H3)(2)C6H3-; Mes = 2,4,6-Me3C6H2-) was prepared and fully characterized. The structural investigation by X-ray crystallography and density functional theory revealed significant distortions in the environment of the ipso carbon and phosphorus centers. These can be traced back to steric interactions and repulsions of the chlorine and methyl substituents on phosphorus with one of the flanking arenes of the m-terphenyl substituents. The primary phosphine 2,6-Mes(2)C(6)H(3)PH(2), 6, and the dimethylphosphine 2,6-(3,5-Me2C6H3)(2) C6H3PMe2, 9, readily form complexes with the Cl2Ru(p-cymene) complex fragment, whereas the larger phosphine 2,6-Mes(2)C(6)H(3)PMe(2), 8, does not. Heating of the complexes TerphPR(2)Ru(Cl-2)(p-cymene) 11 and 12 and the mixture of 8 and {(p-cymene)RuCl2}(2) lead to expulsion of the p-cymene ligand and intramolecular eta(6) coordination of one of the flanking arene rings to the ruthenium center to afford the complexes Cl2RuP(H-2)C6H3-2-eta(6)-Mes-6-Mes, 13, Cl2RuP(Me-2)C6H3-2-eta(6)-Mes-6-Mes, 14, and Cl2RuP(H-2)C6H3-2-eta(6)-(3,5-Me2C6H3)-6-(3,5-Me2C6H3), 15. All complexes were characterized by NMR spectroscopy and complexes 14 and 15 also by X-ray crystallography. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.03.034