[PtCl2(Me3SiO-4-(2,5-C6H2Me2)N=CH-2-Py)] | 1006624-51-6

• 英文名称: [PtCl2(Me3SiO-4-(2,5-C6H2Me2)N=CH-2-Py)]
• CAS: 1006624-51-6
• 化学式: C₁₇H₂₂Cl₂N₂OPtSi
• 分子量: 564.446
• InChiKey: PFIFTKDUQPCVQT-VEWWMAHHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichlorobis(dimethylsulfide)platinum(II) 、 Me3SiO-4-(2,5-Me2Ph)-N=CH-2-Py 以 二氯甲烷 为溶剂， 以78%的产率得到[PtCl2(Me3SiO-4-(2,5-C6H2Me2)N=CH-2-Py)]
  参考文献：
  名称：

  Carbosilane dendrimers containing complexes N,N′-pyridylimine of molybdenum and platinum at their periphery

  摘要：

  Pyridylimine ligands of general formula CS-{O-4-(2,5-C6H2R2)-N=CH-2-Py}(n), where CS is a trimethylsilyl group (n = 1, R = H, Ia or Me, Ib) or a carbosilane dendritic framework (IIa,b, n = 4; IIIa, n = 8), have been coordinated to platinum(II) and molybdenum(O) centers to give the mononuclear [(Ia,b){PtCl2}], tetranuclear [(IIb){PtCl2}(4)] and [(IIb){Mo(CO)(3)(MeCN)}(4)], and octanuclear [(IIIa) {Mo(CO)(3)(MeCN)}(8)] complexes. The poor solubility of the polymetallic platinum compounds impedes the preparation of higher-generation dendrimers, although such a limitation is not found in the case of the more soluble molybdenum dendrimers. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.10.050