lithium rubidium hexafluorotitanate | 150412-99-0

• 英文名称: lithium rubidium hexafluorotitanate
• CAS: 150412-99-0
• 化学式: F₆Ti*Li*Rb
• 分子量: 254.279
• InChiKey: BBYKVJFWLLEUIX-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  lithium hexafluorotitanate 、 rubidium hexafluorotitanate 以 水 为溶剂， 生成 lithium rubidium hexafluorotitanate
  参考文献：
  名称：

  Synthesis and physicochemical investigation of LiMTif6

  摘要：

  Mixed alkali hexafluorotitanates of the composition LiMTiF6 are synthesized, which crystallize with the orthorhombic symmetry. The lattice parameters of these materials are determined It is shown that substitution of the Li+ cation in Li2TiF6 by Na+, K+, Rb+, and Cs+ leads to various degrees of distortion of the hexafluoro-ion It is determined (F-19 NMR data) that the change in the dynamic state of the octahedral [TiF6]2- ions is related to their transition from the hindered-rotational to the isotropic state.

  DOI：

  10.1007/bf00863353