dichloro[3,5:12,14-dipyridyl-8,9:17,18-dibenzo-2,4,6,11,13,14-hexacyclooctadecane-1,6,10,15-tetraene]nickel(II) | 770712-70-4

• 英文名称: dichloro[3,5:12,14-dipyridyl-8,9:17,18-dibenzo-2,4,6,11,13,14-hexacyclooctadecane-1,6,10,15-tetraene]nickel(II)
• CAS: 770712-70-4
• 化学式: C₂₆H₁₈Cl₂N₆Ni
• 分子量: 544.065
• InChiKey: AAHXEABCHOXRIV-WZOSYUFFSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,6-二氨基吡啶 、 nickel(II) chloride hexahydrate 、 邻苯二甲醛 以 甲醇 为溶剂， 以63%的产率得到dichloro[3,5:12,14-dipyridyl-8,9:17,18-dibenzo-2,4,6,11,13,14-hexacyclooctadecane-1,6,10,15-tetraene]nickel(II)
  参考文献：
  名称：

  Synthesis and Characterization of Hexaazamacrocyclic Complexes with Co(II), Ni(II), Cu(II), and Zn(II) Derived from Phthalaldehyde and 2,6‐Diaminopyridine

  摘要：

  A novel family of hexaazamacrocyclic complexes [MLX2] [M = CO(II), Ni(II), Cu(II), and Zn(II), X = Cl or NO3] containing pyridine and imine groups as part of the macrocyclic framework have been synthesized by the condensation of o-phthalaldehyde with 2,6-diaminopyridine in the presence of metal ions as templates in methanol as solvent. The complexes have been characterized on the basis of elemental analyses, IR, H-1 NMR, EPR, UV-Visible, magnetic susceptibility, and conductivity measurements at room temperature. An octahedral geometry has been proposed for all of these complexes. The low conductivity data suggest their non-ionic nature.

  DOI：

  10.1081/sim-120035959