10-(2-hydroxyphenyl)-7-mesityl-10b-(4-methoxyphenyl)-10bH-11-oxa-4b1,10a-diaza-10bl4-boracyclopenta[e]aceanthrylen-10a-ium | 1171817-80-3

• 英文名称: 10-(2-hydroxyphenyl)-7-mesityl-10b-(4-methoxyphenyl)-10bH-11-oxa-4b1,10a-diaza-10bl4-boracyclopenta[e]aceanthrylen-10a-ium
• CAS: 1171817-80-3
• 化学式: C₃₇H₃₁BN₂O₃
• 分子量: 562.476
• InChiKey: DYJMMIJLOJQZPD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (mesityl)C((C4H2N)(C6H4)OH)((C4H3N)(C6H4)OH) 、 4-甲氧基苯硼酸 以 氯仿 为溶剂， 反应 3.0h， 以92%的产率得到10-(2-hydroxyphenyl)-7-mesityl-10b-(4-methoxyphenyl)-10bH-11-oxa-4b1,10a-diaza-10bl4-boracyclopenta[e]aceanthrylen-10a-ium
  参考文献：
  名称：

  Convenient and highly efficient synthesis of boron–dipyrrins bearing an arylboronate center

  摘要：

  Novel boron-dipyrrins bearing an aryl group and a phenyloxy group linked directly to the boron center have been prepared in high yields from arylboronic acid. The unique Coordination geometry around the boron was determined by an X-ray crystallographic analysis. The complexes showed a strong fluorescence, and alkylation of the OH group shifted the emission to a longer wavelength with a larger Stokes shift.

  DOI：

  10.1016/j.tetlet.2009.02.094