{Rh(CO)2(N(CH2(pyrazolyl))3)}BF4 | 137755-80-7

• 英文名称: {Rh(CO)2(N(CH2(pyrazolyl))3)}BF4
• CAS: 137755-80-7
• 化学式: BF₄*C₁₄H₁₅N₇O₂Rh
• 分子量: 503.029
• InChiKey: RVESFUMBOYNJTG-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  {Rh(cycloocta-1.5-diene)(N(CH2(pyrazolyl))3)}BF4 以 二氯甲烷 为溶剂， 以55%的产率得到{Rh(CO)2(N(CH2(pyrazolyl))3)}BF4
  参考文献：
  名称：

  Poly(1-pyrazolyl)boratoiridium and tris(1-pyrazolylmethyl)aminoiridium and -rhodium complexes

  摘要：

  The synthesis of the Ir(H(n)BPz4-n)(cod) (n = 2, 0; Pz = pyrazolyl; cod = cycloocta-1,5-diene) complexes is described. They are prepared by reaction of [Ir(mu-Cl)(cod)]2 with Tl(H(n)BPz4-n). The carbonyl compounds Ir(H(n)BPz4-n)(CO)2 (n = 2, 0) are obtained by carbonylation of the cycloocta-1,5-diene derivatives. The preparations of the [Ir(coe)2{N(CH2Pz)3}]BF4 (coe = cyclooctene) and [M(cod){N(CH2Pz)3}]BF4 (M = Ir, Rh) compounds are also reported. They are prepared by treatment of [Ir(mu-Cl)(coe)2]2 or [M(mu-Cl)(cod)]2 with N(CH2Pz)3 and NaBF4. The carbonyl compound [Rh(CO)2{N(CH2Pz)3}]BF4 is obtained by carbonylation of [Rh(cod){N(CH2Pz)3}]BF4.

  DOI：

  10.1016/s0277-5387(00)83768-7