(η5-C5H5)2Hf(η2-isobutylene)(PMe3) | 127033-21-0

• 英文名称: (η5-C5H5)2Hf(η2-isobutylene)(PMe3)
• CAS: 127033-21-0
• 化学式: C₁₇H₂₆HfP
• 分子量: 439.857
• InChiKey: GWPMJBQTNBOSRX-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  (η5-C5H5)2Hf(η2-isobutylene)(PMe3) 、 三苯基硅烷 以 苯 为溶剂， 以65%的产率得到(η5-C5H5)2Hf(H)(SiPh3)(PMe3)
  参考文献：
  名称：

  锆茂和ha茂金属硅氢化物配合物的合成，表征和反应性

  摘要：

  The trimethylphosphine adducts of zirconocene and hafnocene silyl hydride complexes have been prepared and the X-ray crystal structure of the zirconocene complex has been determined. In addition, the mechanism of formation of these complexes and a study of the reactivity of the zirconocene complex are presented. The complex Cp2Zr(H)(SiPh3)(PMe3) (2) crystallizes in the monoclinic space group P2(1)/c with a = 9.336 (2) angstrom, b = 28.863 (8) angstrom, c = 11.051 (3) angstrom, beta = 111.11 (2)-degrees, and Z = 4; R(w) = 0.048.

  DOI：

  10.1021/om00058a018