titanium tetrachloride bis(nitrosobenzene) | 146190-38-7

• 英文名称: titanium tetrachloride bis(nitrosobenzene)
• CAS: 146190-38-7
• 化学式: C₁₂H₁₀Cl₄N₂O₂Ti
• 分子量: 403.916
• InChiKey: DMMCPDQJWNCHQO-IGMKIZKBSA-J

反应信息

• 作为产物：
  描述：

  四氯化钛 、 亚硝基苯 以 二氯甲烷 为溶剂， 以59%的产率得到titanium tetrachloride bis(nitrosobenzene)
  参考文献：
  名称：

  The coordination complexes of nitrosobenzene with tin(IV) chloride and titanium(IV) chloride

  摘要：

  Coordination complexes of nitrosobenzene with tin and titanium tetrachlorides have been prepared and subjected to solid-state C-13 NMR spectroscopy. The absence of resonances above 160 ppm characteristic of C-NO and the presence of resonances of quaternary carbons in the range characteristic of C-N2O2-C suggests that the cis-dimer of nitrosobenzene is acting as a bidentate donor.

  DOI：

  10.1016/s0277-5387(00)83636-0