(S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron | 138332-59-9

• 英文名称: (S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron
• CAS: 138332-59-9
• 化学式: C₄₈H₃₇FeO₂P
• 分子量: 732.641
• InChiKey: LOBLUOMLEJMICO-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  (S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron 在 triphenyl phosphine 作用下， 以 氘代苯 为溶剂， 生成 rac-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron
  参考文献：
  名称：

  手性[（联萘基二基二亚甲基）环戊二烯基]铁配合物（BpDMCp）Fe（CO）2CH3的不对称迁移插入反应

  摘要：

  The migratory insertion reaction of a (cyclopentadienyl)methyliron dicarbonyl 2 containing the chiral (binaphthyldiyldimethylene)cyclopentadienyl ligand 1 in the presence of triphenylphosphine can proceed with modest diastereoselectivity. The resulting acyliron complexes 5 are separable and are configurationally stable under oxidative conditions.

  DOI：

  10.1021/om00038a076
• 作为产物：
  描述：

  在 triphenyl phosphine 、 (NH₄)2Ce(NO₃)6 、 C₁₀H₈Na 作用下， 以 乙腈 为溶剂， 生成 (S,S)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron 、 (S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron
  参考文献：
  名称：

  手性[（联萘基二基二亚甲基）环戊二烯基]铁配合物（BpDMCp）Fe（CO）2CH3的不对称迁移插入反应

  摘要：

  The migratory insertion reaction of a (cyclopentadienyl)methyliron dicarbonyl 2 containing the chiral (binaphthyldiyldimethylene)cyclopentadienyl ligand 1 in the presence of triphenylphosphine can proceed with modest diastereoselectivity. The resulting acyliron complexes 5 are separable and are configurationally stable under oxidative conditions.

  DOI：

  10.1021/om00038a076