[(TiCl2(μ-(OB(NHMe2)-η5-C5H4)))2-μ-O] | 879084-09-0

• 英文名称: [(TiCl2(μ-(OB(NHMe2)-η5-C5H4)))2-μ-O]
• CAS: 879084-09-0
• 化学式: C₁₄H₂₂B₂Cl₄N₂O₃Ti₂
• 分子量: 525.534
• InChiKey: HFBOZRWVZNOHPL-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Ti((η5-C5H4)B(N(i)Pr2)N(H)(t)Bu)Cl2(NMe2)] 、 水 以 二氯甲烷 为溶剂， 生成 [(TiCl2(μ-(OB(NHMe2)-η5-C5H4)))2-μ-O]
  参考文献：
  名称：

  Derivatisation of boryl substituted titanium half-sandwich complexes – Molecular structures of [Ti{(η5-C5H4)B(NiPr2)N(H)tBu}Cl2(NMe2)] and [{TiCl2(μ-{OB(NHMe2)-η5-C5H4})}2-μ-O]

  摘要：

  The half-sandwich complex [Ti{eta(5)-C5H4)B(NiPr2)N(H)iPr}(NMe2)(3)] (6) was prepared from (eta(5)-C5H5)B(NiPr2)N(H)iPr (5) and [Ti(NMe2)(4)] with cleavage of one equivalent of HNMe2 and further converted into the corresponding constrained geometry complex [Ti{(eta(5)-C5H4)B(NiPr2)NiPr} (NMe2)(2)] (7) by elimination of a second equivalent of HNMe2. Reaction of the half-sandwich complexes [Ti{(eta(5)-C5H4)B(NiPr2)N(H)R}(NMe2)(3)] (R = iPr, tBu) with excess Me3SiCl yielded the corresponding dichloro complexes [Ti{(eta(5)-C5H4)B(NiPr2)N(H)R}Cl-2(NMe2)] (R = tBu (10), iPr (11)). The intermediate species [Ti{(eta(5)-C5H4)B(NiPr2)N(H)iPr}Cl(NMe2)(2)] (9) could also be spectroscopically characterised. Partial hydrolysis of 10 and 11, respectively, resulted in formation of [{TiCl2(mu-OB(NHMe2)-eta(5)-C5H4}))(2)-mu-O] (12). The molecular structures of 10 and 12 have been determined by X-ray crystallographic analyses. Complex 10, when activated with MAO, was found to be a highly active styrene polymerisation catalyst while being inactive towards the polymerisation of ethylene. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.10.008