[(2-((methyl)2NCH2)C6H4)(2-((methyl)2NHCH2)C6H4)SnCl2][(2-((methyl)2NCH2)C6H4)SnCl4] | 911858-77-0

• 英文名称: [(2-((methyl)2NCH2)C6H4)(2-((methyl)2NHCH2)C6H4)SnCl2][(2-((methyl)2NCH2)C6H4)SnCl4]
• CAS: 911858-77-0
• 化学式: C₉H₁₂Cl₄NSn*C₁₈H₂₅Cl₂N₂Sn
• 分子量: 853.749
• InChiKey: DQAJRSWLMXCCOL-UHFFFAOYSA-I

反应信息

• 作为反应物：
  描述：

  [(2-((methyl)2NCH2)C6H4)(2-((methyl)2NHCH2)C6H4)SnCl2][(2-((methyl)2NCH2)C6H4)SnCl4] 、 potassium bromide 以 二氯甲烷 、 水 为溶剂， 生成 dibromo[2-(dimethylaminomethyl)phenyl][2-(dimethylammoniomethyl)phenyl]tin(IV) tetrabromo[2-(dimethylaminomethyl)phenyl]tin(IV)
  参考文献：
  名称：

  Hydrogen bonding in dibromo[2-(dimethylaminomethyl)phenyl][2-(dimethylammoniomethyl)phenyl]tin(IV) tetrabromo[2-(dimethylaminomethyl)phenyl]tin(IV)

  摘要：

  The molecular structure of the title compound, [SnBr2-( C9H12N)(C9H13N)][ SnBr4(C9H12N)], consists of a dibromobis[ 2-( dimethylaminomethyl) phenyl][ 2- dimethylammoniomethyl) phenyl] tin(IV) cation and a tetrabromo[ 2-( dimethylaminomethyl) phenyl] tin( IV) anion. As a result of strong intramolecular N -> Sn interactions, distorted trigonal-bipyramidal and octahedral coordination geometries are established for the metal centres of the diorganotin( IV) and monoorganotin( IV) fragments, respectively. The cation and anion are linked together by two Br (...) H contacts, while three additional similar contacts result in a dimeric fragment which repeats in a two-dimensional supramolecular arrangement.

  DOI：

  10.1107/s010827010605150x