| 175285-84-4

• CAS: 175285-84-4
• 化学式: C₆H₁₈AsCl₅N₂P₂Sn
• 分子量: 551.066
• InChiKey: FFKULSJRYPZZOV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四氯化锡 、 以 二氯甲烷 为溶剂， 以97.5%的产率得到
  参考文献：
  名称：

  Phosphaniminato‐Komplexe des Arsens. Kristallstrukturen von [AsCl(NPMe ₃ )] ₂ Cl ₂ , [AsCl(NPMe ₃ ) ₂ SbCl ₄ ]SbCl ₆ und [AsCl(NPMe ₃ ) ₂ SnCl ₄ ] · CH ₃ CN

  摘要：

  Phosphane Iminato Complexes of Arsenic. Crystal Structures of [AsCl(NPMe3)]2Cl2, [AsCl(NPMe3)2SbCl4]SbCl6, and [AsCl(NPMe3)2SnCl4] · CH3CN[AsCl(NPMe3)]2Cl2 (1) was prepared by the reaction of arsenic trichloride with the silylated phosphane imine Me3‐SiNPMe3 in acetonitrile solution. According to the crystal structure determination, 1 has an ionic structure with [AsCl(NPMe3)]22+ ions, in which the As atoms are linked by the μ2‐N atoms of the NPMe3– groups. Compound 1 reacts with antimony pentachloride to give [AsCl(NP‐Me3)2SbCl4]+SbCl6– (2), with tin tetrachloride to form [AsCl(NPMe3)2SnCl4] (3), which is isoelectronic to the cation of 2. In 2 and 3 AsCl(NPMe3)2 acts as a chelating agent forming and , respectively, four‐membered ring structures.

  DOI：

  10.1002/cber.19961290120