[Pd(κ2-N,C-benzophenone oxime)(triphenylphosphine)(Cl)] | 30471-26-2

• 英文名称: [Pd(κ2-N,C-benzophenone oxime)(triphenylphosphine)(Cl)]
• CAS: 30471-26-2；1145982-27-9
• 化学式: C₃₁H₂₅ClNOPPd
• 分子量: 600.392
• InChiKey: JIUSBGLRSMIRSA-KXVYGGSGSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二苯甲酮肟 以 氯仿 为溶剂， 生成 [Pd(κ2-N,C-benzophenone oxime)(triphenylphosphine)(Cl)]
  参考文献：
  名称：

  NC palladacycles in the Heck arylation of ethylene: Synthesis, structure and their reactivity

  摘要：

  Monomeric cyclopalladated complexes with NC coordination using ligands 2-phenylpyridine, 2-phenylquinoline, 8-methylquinoline have been synthesized and the structures have been determined by single crystal X-ray structure analysis. The crystal structures of monomeric palladacycles prepared using benzophenone oxime, and 2-phenylpyridine have also been determined. The use of these complexes in the Heck arylation of ethylene with 2-bromo-6-methoxynaphthalne (BMN) to give 2-vinyl-6-methoxynapthalene which is an intermediate for the synthesis of anti-inflammatory drug Naproxen has been examined and also arylation of ethylene with 3-bromo-benzophenone and 4-bromo-isobutylbenzene was investigated. These palladacycles with NC coordination show excellent catalytic activity with a TOF > 4000 h (1). (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.11.065