gallium-tris{(2-hydroxy-5-isopropyl-benzylidenimino)ethyl}amine | 137322-92-0

• 英文名称: gallium-tris{(2-hydroxy-5-isopropyl-benzylidenimino)ethyl}amine
• CAS: 137322-92-0
• 化学式: C₃₆H₄₅GaN₄O₃
• 分子量: 651.501
• InChiKey: JEYLEPSVJMZMBO-QMPBXKDZSA-K

反应信息

• 作为产物：
  描述：

  galium(III) nitrate monohydrate 、 tris{2-(2'-hydroxy-5'-isopropylbenzylideneamino)ethyl}amine 在 sodium acetate 作用下， 以 乙醇 为溶剂， 以61%的产率得到gallium-tris{(2-hydroxy-5-isopropyl-benzylidenimino)ethyl}amine
  参考文献：
  名称：

  Synthesis, stereochemical characterisation and absolute configuration of enantiomerically pure complexes of sexidentate ligands

  摘要：

  The optically active sexidentate Schiff bases [H3L5] and [H3L6] were prepared from tris[(S)-2-aminopropyl]amine and 5-chlor- and 5-isopropylsalicylaldehyde, respectively. Reaction of rhodium trichloride with [H3L6] gave an enantiomerically pure [RhL6] complex with an absolute configuration of LAMBDA-for the octahedral arrangement. The chiroptical properties are given.

  DOI：

  10.1007/bf00809812