| 286384-34-7

• CAS: 286384-34-7
• 化学式: C₁₃H₁₉N₃O₂*F₆P
• 分子量: 394.277
• InChiKey: JNCOMJFUAONJLZ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Structures and Magnetic Properties of [o- andp-MePyNN⁺]₂[Cu(ox)₂] (MePyNN⁺= Nitronyl Nitroxyl Radical Cation)

  摘要：

  Reactions of [o-MePyNN+]PF6 and [p-MePyNN+]PF6 with [n-Bu4N]2[Cu(ox)2] in acetonitrile yielded dark-blue crystals of [o-MePyNN+]2[Cu(ox)2]·2CH3OH (1) and [p-MePyNN+]2[Cu(ox)2]·2H2O (2), respectively, where [o-MePyNN+] or [p-MePyNN+] represents the 2-(2 or 4-N-methylpyridinium)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazo-1-oxyl 3-oxide radical cation. X-ray structural analyses showed that the crystals of 1 and 2 are isomorphous. The coordination geometry of the Cu2+ ions in 1 and 2 is an elongated octahedron, and the equatorial and apical coordination sites of the Cu2+ ions are occupied by two oxalato groups and two radial cations, respectively. Magnetic susceptibility measurements for 1 and 2 revealed that the copper and radical centers are ferromagnetically coupled with J = +8.2(1) and +7.8(1) cm-1 (H = -2J∑SCu·Srad), respectively.

  DOI：

  10.1246/bcsj.73.1365