| 138062-28-9

• CAS: 138062-28-9
• 化学式: C₄₈H₅₀Ru₂
• 分子量: 829.065
• InChiKey: ZYVDHIRMRIANPS-CJUVLIERSA-N

反应信息

• 作为产物：
  描述：

  tetra-μ-hydrido-bis[(pentamethyl-η5-cyclopentadienyl)ruthenium] 、 二苯基乙炔 以 甲苯 为溶剂， 以14%的产率得到
  参考文献：
  名称：

  含垂直桥联二苯乙炔配体的双核二氢化钌配合物的合成和分子结构

  摘要：

  The reaction of a dinuclear tetrahydridoruthenium complex (eta(5)-C5Me5)Ru(mu-H)4Ru(eta(5)-C5Me5) (1) with 2 equiv of diphenylacetylene results in the formation of the dinuclear ruthenium dihydride complex (eta(5)-C5Me5)Ru(mu-H)2(mu-PhCCPh)Ru(eta(5)-C5Me5) (2), which contains a perpendicularly bridging diphenylacetylene ligand. The complex crystallizes in the triclinic system, in space group P1, with a = 10.284 (4) angstrom, b = 15.871 (4) angstrom, c = 10.286 (3) angstrom, alpha = 98.47 (3)-degrees, beta = 110.92 (2)-degrees, alpha = 98.22 (3)-degrees, V = 1515.8 (9) angstrom 3, and Z = 2. Anisotropic refinement of all atoms except hydrogen atoms converged to the residuals R = 0.0569 and R(w) = 0.0539 for 6177 reflections.

  DOI：

  10.1021/om00038a079