| 157261-52-4

• CAS: 157261-52-4
• 化学式: C₂₄H₃₄Co₂S₂
• 分子量: 504.652
• InChiKey: GYSUOJBQZKHETF-RFUWXRFNSA-N

反应信息

• 作为产物：
  描述：

  在 H₂S 作用下， 以 苯 为溶剂， 以24%的产率得到
  参考文献：
  名称：

  Carbon-sulfur bond cleavage by cobalt. Reaction of Cp★Co(C2H4)2 with dibenzothiophene

  摘要：

  The thermal reaction of Cp*Co(C2H4)2 with thiophene yields the C-S insertion product [CP*Co]2(mu-eta2,eta3-C4H4S). Reaction with dibenzothiophene produces the analogous dinuclear C-S insertion adduct [CP*Co]2(mu-eta2,eta3-C12H8S) the crystal structure of which was determined. Reaction of the thiophene insertion adduct with H2S gives a new butadienedithiolate compound in which sulfur has inserted into the metal-carbon bond, [CP*Co]2(mu-eta2,eta2-S2C4H4).

  DOI：

  10.1016/0022-328x(94)80217-3