| 1178892-63-1

• CAS: 1178892-63-1
• 化学式: C₅₀H₄₆Fe₂O₄P₂
• 分子量: 884.554
• InChiKey: AZCFDJHXMIKWBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  exo,exo,syn-1,12-dichloro-1,12-diphospha[1.1]ferrocenophane 、 在 BH₃ 、 HNEt₂ 作用下， 以 not given 为溶剂， 以13%的产率得到
  参考文献：
  名称：

  Synthesis of Binuclear Complexes Bound in an Enlarged Tetraphosphamacrocycle: Two Diphosphine Metal Units Linked in Front-to-Front Style

  摘要：

  A large-hole tetraphosphamacrocycle 2, with four phosphorus centers separated at the corners of a 3.7 angstrom wide and 9.7 angstrom long rectangle, was synthesized by a stepwise cyclization reaction between PCI-bridged [1.1]ferrocenophane and bisphenol A in a 2:2 ratio. The macrocycle 2 could incorporate two Ag+ or Pt-0 fragments in the hole to provide binuclear complexes, which were identified as mu-2-[Ag(NCMe)(2)](2)(BF4)(2) (3) and mu-2-[Pt(PhCCPh)](2) (5), respectively, using X-ray and spectroscopic analysis. The X-ray structure of 3 demonstrates that the macrocycle 2 serves as a framework in which two diphosphine silver units are aligned in a front-to-front style, while that of 5 indicates that 2 can also bind two bulky Pt(PhCCPh) fragments by the flexible change of its conformation.

  DOI：

  10.1021/ic9013224
• 作为产物：
  描述：

  exo,exo,syn-1,12-dichloro-1,12-diphospha[1.1]ferrocenophane 、 4-[1-(4-{[tert-butyl(dimethyl)silyl]oxy}phenyl)methylethyl]phenol 在 Bu₄NF 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of Binuclear Complexes Bound in an Enlarged Tetraphosphamacrocycle: Two Diphosphine Metal Units Linked in Front-to-Front Style

  摘要：

  A large-hole tetraphosphamacrocycle 2, with four phosphorus centers separated at the corners of a 3.7 angstrom wide and 9.7 angstrom long rectangle, was synthesized by a stepwise cyclization reaction between PCI-bridged [1.1]ferrocenophane and bisphenol A in a 2:2 ratio. The macrocycle 2 could incorporate two Ag+ or Pt-0 fragments in the hole to provide binuclear complexes, which were identified as mu-2-[Ag(NCMe)(2)](2)(BF4)(2) (3) and mu-2-[Pt(PhCCPh)](2) (5), respectively, using X-ray and spectroscopic analysis. The X-ray structure of 3 demonstrates that the macrocycle 2 serves as a framework in which two diphosphine silver units are aligned in a front-to-front style, while that of 5 indicates that 2 can also bind two bulky Pt(PhCCPh) fragments by the flexible change of its conformation.

  DOI：

  10.1021/ic9013224