[(η5-C6H6(Me))Mn(CO)3] | 59653-72-4

• 英文名称: [(η5-C6H6(Me))Mn(CO)3]
• CAS: 59653-72-4
• 化学式: C₁₀H₉MnO₃
• 分子量: 232.118
• InChiKey: CLBKTFMQAPNOSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  nitrosyl hexafluorophosphate 、 [(η5-C6H6(Me))Mn(CO)3] 以 二氯甲烷 为溶剂， 以83%的产率得到{dicarbonylnitrosyl(cyclohexadienyl(methyl))manganese}{PF6}
  参考文献：
  名称：

  二羰基亚硝基（环己二烯基）锰阳离子的合成和亲电反应性：配位芳烃的双亲核加成

  摘要：

  合成这些脱阳离子（环己二烯基）Mn（CO）（NO）L + 脱（环己二烯基）Mn(CO) 2 L (L=CO, PBu 3 ) avec NOPF 6 。亲核试剂减少阳离子的反应机理

  DOI：

  10.1021/ja00294a032
• 作为产物：
  描述：

  benzenetricarbonylmanganese hexafluorophosphate 以 二氯甲烷 为溶剂， 生成 [(η5-C6H6(Me))Mn(CO)3]
  参考文献：
  名称：

  Gaudet, Michele V.; Hanson, Alfred W.; White, Peter S., Organometallics, 1989, vol. 8, # 2, p. 286 - 293

  摘要：

  DOI：

文献信息

• The lithium aluminium hydride reduction of cyclohexadienylmanganese complexes
  作者：Peter Bladon、George A.M. Munro、Peter L. Pauson、Christopher A.L. Mahaffy

  DOI：10.1016/s0022-328x(00)81031-1

  日期：1981.11

  Reduction of cyclohexadienyltricarbonylmanganese or its ring-substituted derivatives with lithium aluminium hydride leads to dihydro-derivatives. Preparative and NMR spectral information is presented and interpreted on the basis of the CH-bridged cyclohexenyl structure recently established for these products by Lamanna and Brookhart [3].

  用氢化锂铝还原环己二烯基三羰基锰或其环取代的衍生物会生成二氢衍生物。制备和NMR光谱信息是根据Lamanna和Brookhart [3]最近为这些产品建立的CH桥环环己烯基结构给出和解释的。
• Brookhart; Lamanna; Pinhas, Allan R., Organometallics, 1983, vol. 2, # 5, p. 638 - 649
  作者：Brookhart、Lamanna、Pinhas, Allan R.

  DOI：——

  日期：——
• Photochemical Rearomatization and Dearomatization of Tricarbonyl(η⁵-cyclohexadienyl)manganese Complexes
  作者：Li Zhou、Li-Zhu Wu、Li-Ping Zhang、Chen-Ho Tung

  DOI：10.1021/om050953b

  日期：2006.3.1

  Photoirradiation of the tricarbonyl(eta(5)-cyclohexadienyl)manganese complexes 2 in dichloromethane or cyclohexane leads to the formation of the rearomatization products 3 in high yield, while photoirradiation of 2 in acetonitrile or dimethylformamide results in 3 and deaxomatization products 5 and 6 with the ratio 1(5 + 6) of ca. 1:1. In the presence of acetic acid the photochemical reaction of 2 both in dichloromethane and in acetonitrile exclusively yields 5 and 6. The photochemical reaction of 2 might be of significant utility in the synthesis of functionalized arenes and substituted cyclohexadienes.
• Synthesis and reactions of acyl(cyclohexadienyl)manganates
  作者：John B. Sheridan、Ranbir S. Padda、Karen Chaffee、Chenjie Wang、Yazhong Huang、Roger Lalancette

  DOI：10.1039/dt9920001539

  日期：——

  The cyclohexadienyl complexes [Mn(eta-5-C6H6R1)(CO)3] 1 (R1 = exo-H, Me or C6H4Me-4) react with LiR2 (R2 = Me or Ph) to give acylmetalates [Li(OEt2)][Mn(eta-5-C6H6R1)(CO)2C(O)R2}] 2. Complex 2 (R1 = Me, R2 = Ph) has been characterised by an X-ray crystallographic study: orthorhombic, space group P2(1)2(1)2(1), a = 9.113(2), b = 14.491(8), c = 32.803(9) angstrom, R = 0.064 for 1458 independent reflections. Protonation of 2 with HBF4.Et2O induces an aryl- or alkyl-group transfer to the endo face of the cyclohexadienyl ring yielding the new agostic cyclohexenyl complexes [Mn(eta(3:CH)C6H7R1R2)(CO)3] 3. The cyclohexenyl ligands can be decomplexed from the metal via treatment of 3 with 1,2-bis-(diphenylphosphino)ethane (dppe) in tetrahydrofuran to afford mixtures of substituted cyclohexa-1,3-dienes and [MnH(CO)3(dppe)]. The acylmetalates 2 react with [NO][BF4] at -78-degrees-C to give [Mn(eta-5-C6H6R1)(CO)(NO)C(O)R2}] which decompose at room temperature to form the trans-disubstituted acylcyclohexadienes C6H6R1[C(O)R2]. Reaction of 2 with electrophiles SiMe3Cl, [Me3O][BF4] or [Et3O][BF4] results in O alkylation and formation of stable carbene complexes [Mn(eta-5-C6H6R1)(CO)2-C(OE)R2}] (E = SiMe3, Me or Et).
• Synthesis and electrophilic reactivity of dicarbonyl(cyclohexadienyl)nitrosylmanganese cations
  作者：Y. K. Chung、Hyung Soo Choi、D. A. Sweigart、Neil G. Connelly

  DOI：10.1021/ja00379a034

  日期：1982.7