(2-dimethylaminomethylcymantrenyl)methyl 2-dimethylaminomethylferrocenecarboxylate | 180334-64-9

• 英文名称: (2-dimethylaminomethylcymantrenyl)methyl 2-dimethylaminomethylferrocenecarboxylate
• CAS: 180334-64-9
• 化学式: C₂₆H₂₉FeMnN₂O₅
• 分子量: 560.312
• InChiKey: CIKQGDILSCTBKA-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  (2-dimethylaminomethylcymantrenyl)methyl 2-dimethylaminomethylferrocenecarboxylate 在 sodium hydroxide 作用下， 以 甲醇 为溶剂， 生成 α-hydroxymethyl(N,N,-dimethylaminomethyl)cymantrene
  参考文献：
  名称：

  Diastereoselectivity in the induction of planar chirality in prochiral cymantrenes

  摘要：

  The carbonylation of the (S)-enantiomer of the palladated derivative of dimethylaminomethylferrocenein the presence of 1,2-bis(hydroxymethyl)cymantrene affords a product containing a chiral plane predominantly of the (R)-configuration. The extent of asymmetric induction amounts to 30-35 %.

  DOI：

  10.1007/bf00697050
• 作为产物：
  描述：

  (2-hydroxymethylcymantrenyl)methyl 2-dimethylaminomethylferrocenecarboxylate 、 二甲胺 在 盐酸 作用下， 以 二氯甲烷 为溶剂， 以53.8-62的产率得到(2-dimethylaminomethylcymantrenyl)methyl 2-dimethylaminomethylferrocenecarboxylate
  参考文献：
  名称：

  Diastereoselectivity in the induction of planar chirality in prochiral cymantrenes

  摘要：

  The carbonylation of the (S)-enantiomer of the palladated derivative of dimethylaminomethylferrocenein the presence of 1,2-bis(hydroxymethyl)cymantrene affords a product containing a chiral plane predominantly of the (R)-configuration. The extent of asymmetric induction amounts to 30-35 %.

  DOI：

  10.1007/bf00697050