| 157174-14-6

• CAS: 157174-14-6
• 化学式: C₄₄H₃₀Fe₄O₁₀P₂Se₄
• 分子量: 1319.89
• InChiKey: HRLSPTBXDSVYGS-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  [(μ-Se)2Fe2(CO)6] 在 sodium acetate 、 N-trimethylamineoxide 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Carbon-selenium bond cleavage in the double butterfly complex [{(CO)6Fe2(μ-Se)2}2{C(Ph)C(H)}] and the synthesis and X-ray structural analysis of its dppe-substituted derivative

  摘要：

  At room temperature, the double butterfly complex [{(CO)6Fe2(mu-Se)2}2(C(Ph)-C(H)] reacted with Pt(C2H4)(PPh3)2 to give [(CO)6Fe2(mu-SeC(Ph)C(H)Se)], [(CO)6Fe2Pt(PPh3)2(mu-SeC(Ph)C(H)Se}] and [(CO)6Fe2(mu3-Se)2Pt(PPh3)2]. It reacted with dppe to form the substituted derivative [{(CO)5Fe2(mu-Se)2}2C(Ph)C(H)(mu-dppe)], which was subjected to an X-ray diffraction analysis. The crystal of [{(CO)5Fe2(mu-Se)2}2C(Ph)C(H)(mu-dppe)] is triclinic with the space group P1BAR, a = 12.969(1), b = 13.032(1), c = 18.669(1) angstrom, alpha = 76.81(1), beta = 72.74(1), gamma = 63.99(1)degrees, Z = 2. The structure was refined by the block-matrix least squares method. The final R and R(w) values were 0.0435 and 0.0492 respectively.

  DOI：

  10.1016/0022-328x(94)88124-3