μ-benzenethiolato-μ-tert-butylimido-chlorobis(η-pentamethylcyclopentadienyl)diruthenium(III) | 185259-06-7

• 英文名称: μ-benzenethiolato-μ-tert-butylimido-chlorobis(η-pentamethylcyclopentadienyl)diruthenium(III)
• CAS: 185259-06-7
• 化学式: C₃₀H₄₄ClNRu₂S
• 分子量: 688.345
• InChiKey: HNFXIRXBHATOQW-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  Li(ButNSPh) 、 以 甲苯 为溶剂， 以10%的产率得到(N-tert-butylbenzenesulfenamido)chloro(η(4)-1,2,3,4-tetramethylfulvene)ruthenium(II)
  参考文献：
  名称：

  Synthesis and crystal structures of η²-sulfenamido complexes of ruthenium and nickel, and of chromium imido and cobalt iminophosphorane complexes via sulfenamido rearrangement

  摘要：

  The interaction of [Ru(eta-C(5)Me(5))Cl-2](2) with Li(Bu(t)NSPh), gave two products, Ru(eta(4)-C(5)Me(4)CH(2))(eta(2)-Bu(t)NSPh)Cl 1 and the dimer Cl(eta-C(5)Me(5))Ru(mu-NBu(t))(mu-SPh)Ru(eta-C(5)Me(5)) 2; the former is best described as a eta(4)-tetramethylfulvene ruthenium(II) complex, while in the latter the bridging tert-butylimido and benzene-thiolato groups were formed by S-N cleavage of sulfenamido species. A similar cleavage resulted in the formation of Cr-V(eta-C(5)Me(5))(NBu(t))(SPh)(2) 3, in the interaction of Li(Bu(t)NSPh) with [Cr(eta-C(5)Me(5))Br-2](2). Interaction of CoCl2(PMe(3))(3) with Li(p-MeC(6)H(4)NSPh) gave the iminophosphorane complex Co(p-MeC(6)H(4)NPMe(3))(2)(SPh)(2) 4. Interaction of NiCl2(PMe(3))(2) with Li(Bu(t)NSPh) gave Ni(eta(2)-Bu(t)NSPh)(2)(PMe(3)) 5. The structures of compounds 1-5 have been confirmed by X-ray crystallography.

  DOI：

  10.1039/dt9960004063