trans,trans-[(2,2':6',2''-terpyridine)(Cl)2Os(III)(μ-1,3-(15)N=(15)N=(15)N)Os(III)(Cl)2(2,2':6',2''-terpyridine)]PF6 | 510707-85-4

• 英文名称: trans,trans-[(2,2':6',2''-terpyridine)(Cl)2Os(III)(μ-1,3-(15)N=(15)N=(15)N)Os(III)(Cl)2(2,2':6',2''-terpyridine)]PF6
• CAS: 510707-85-4
• 化学式: C₃₀H₂₂Cl₄N₉Os₂*F₆P
• 分子量: 1178.72
• InChiKey: PCDJFHCVVNTZNE-ZHGRTRLKSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  {osmiumnitrido(chloro)2(η3-2,2':6',2''-terpyridine)}PF6 、 15N-氨 在 氧气 作用下， 以 乙腈 为溶剂， 生成 trans,trans-[(2,2':6',2''-terpyridine)(Cl)2Os(III)(μ-1,3-(15)N=(15)N=(15)N)Os(III)(Cl)2(2,2':6',2''-terpyridine)]PF6
  参考文献：
  名称：

  Multiple Mixed-Valence Behavior in trans,trans-[(tpy)(Cl)₂Os^III(μ-1,3-N₃)Os^III(Cl)₂(tpy)]⁺. An Azido Bridge from the Reaction between trans-[Os^VI(tpy)(Cl)₂(N)]⁺ and NH₃

  摘要：

  Reaction between the Os(VI)-nitrido complex, trans-[OsVI(tpy)(Cl)2(N)]PF6 (tpy = 2,2':6',2' '-terpyridine), and ammonia (NH3) under N2 in dry CH3CN gives the mu-1,3-azido bridged [OsII-N3-OsII]- dimer, trans,trans-NH4[(tpy)(Cl)2OsII(N3)OsII(Cl)2(tpy)]. It undergoes air oxidation to give the [OsIII-N3-OsIII]+ analogue, trans,trans-[(tpy)(Cl)2OsIII(N3)OsIII(Cl)2(tpy)]PF6 ([OsIII-N3-OsIII]PF6), which has been isolated and characterized. The structural formulation as a mu-1,3-N3 bridged complex has been established by infrared and 15N NMR measurements on the 15N-labeled forms, [OsIII-14N=15N=14N-OsIII]+, [OsIII-15N=14N=15N-OsIII]+, and [OsIII-15N=15N=15N-OsIII]+. Cyclic voltammetric measurements in 0.2 M Bu4NPF6/CH3CN reveal the existence of five chemically reversible waves from 1.40 to -0.12 V for couples ranging from OsV-OsIV/OsIV-OsIV to OsIII-OsII/OsII-OsII. DeltaE1/2 values for couples adjacent to the three mixed-valence forms are 0.19 V for OsIII-OsII, 0.52 V for OsIV-OsIII, and >0.71 V for OsV-OsIV. In CH3CN at 60 degrees C, [OsIII-N3-OsIII]+ undergoes a [2 + 3] cycloaddition with CH3CN at the mu-N3- bridge followed by a solvolysis to give trans-[OsIII(tpy)(Cl)2(5-MeCN4)] and trans-[OsIII(tpy)(Cl)2(NCCH3)]PF6.

  DOI：

  10.1021/ja021324l