| 22026-81-9

• CAS: 22026-81-9
• 化学式: C₁₃H₈Br₂HgMoN₂O₃
• 分子量: 696.556
• InChiKey: KFIREABBNQJNME-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  、 tin(II) bromide 以 甲醇 、 二氯甲烷 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Reactivity of carbonyl complexes containing MoHg bonds; reaction of tin(II) halides with [Mo(CO)3(NN)(HgX)(X)] (NN = bpy, phen, dmp); crystal structure of [Mo(CO)3(dmp)(HgCl)(Cl)]

  摘要：

  Reaction of HgCl2 with [Mo(CO),(dmp)] (dmp = 2,9-dimethyl-1,10-phenanthroline) gives the heterobimetallic compound [MO(CO)3(dmp)(HgCl)(Cl)] (I), which gives rise to a new compound [Mo(CO)3(dmp)(HgCl)(Cl)] . 1/2(CH3)2CO (II) in acetone solution at low temperature. The crystal structure of I has been solved and the compound shown to be a capped trigonal prism containing Mo-Hg-Cl and Mo-Cl bonds. The reactions of the above and related heteronuclear complexes [MO(CO)3(NN)(HgX)(X)] [X = Cl, Br; NN = 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen)] with tin (II) halides were studied. No insertion of the latter into the metal-metal or metal-halogen bonds were observed, with only bimetallic tricarbonyl complexes containing Mo-Hg bonds being isolated.

  DOI：

  10.1016/s0277-5387(00)80095-9