1-ferrocenyl-3-ruthenocenylpropane-1,3-dione | 436141-76-3

• 英文名称: 1-ferrocenyl-3-ruthenocenylpropane-1,3-dione
• 英文别名: ferrocenoylruthenocenoylmethane
• CAS: 436141-76-3
• 化学式: C₂₃H₂₀FeO₂Ru
• 分子量: 485.328
• InChiKey: BAWGFQLSEABMRU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1-ferrocenyl-3-ruthenocenylpropane-1,3-dione 以 neat (no solvent, solid phase) 为溶剂， 生成 1-ferrocenyl-3-ruthenocenylpropane-1,3-dione
  参考文献：
  名称：

  含钌茂金属的β-二酮：合成，p K a ′值，酮-烯醇异构化动力学和电化学方面

  摘要：

  在受阻碱二异丙基氨基锂的影响下，将乙酰基钌茂金属与适当的甲酯RCOOMe进行克莱森缩合，得到β-二酮（RcCOCH 2 COR）1-钌茂金属-4,4,4-三氟丁烷-1,3-二酮（钌烷基乙酰基三氟丙酮，1，R = CF 3 ; p K a '= 7.36±0.03），1-钌烯基丁烷-1,3-二酮（钌乙基乙酰基丙酮，2，R = CH 3 ; p K a '= 10.22±0.01），1-苯基-3-钌烯基丙烷-1,3-二酮（苯甲酰钌烯基甲烷，3，R = C 6 H 5 ; p K a′= 11.31±0.03），1-二茂铁基-3-钌烯基丙烷-1,3-二酮（二茂铁基钌烯基乙酰基甲烷，4，R = Fc =（C 5 H 5）Fe（C 5 H 4）=二茂铁基; p K a '=大约12.8）和1,3-十二碳烯基丙烷-1,3-二酮（十二碳烯基甲烷，5，R = Rc =（C 5 H 5）Ru（C 5 H 4）=钌烯基;

  DOI：

  10.1021/om700609z
• 作为产物：
  描述：

  1-ferrocenyl-3-ruthenocenylpropane-1,3-dione 以 氘代氯仿 为溶剂， 生成 1-ferrocenyl-3-ruthenocenylpropane-1,3-dione
  参考文献：
  名称：

  含钌茂金属的β-二酮：合成，p K a ′值，酮-烯醇异构化动力学和电化学方面

  摘要：

  在受阻碱二异丙基氨基锂的影响下，将乙酰基钌茂金属与适当的甲酯RCOOMe进行克莱森缩合，得到β-二酮（RcCOCH 2 COR）1-钌茂金属-4,4,4-三氟丁烷-1,3-二酮（钌烷基乙酰基三氟丙酮，1，R = CF 3 ; p K a '= 7.36±0.03），1-钌烯基丁烷-1,3-二酮（钌乙基乙酰基丙酮，2，R = CH 3 ; p K a '= 10.22±0.01），1-苯基-3-钌烯基丙烷-1,3-二酮（苯甲酰钌烯基甲烷，3，R = C 6 H 5 ; p K a′= 11.31±0.03），1-二茂铁基-3-钌烯基丙烷-1,3-二酮（二茂铁基钌烯基乙酰基甲烷，4，R = Fc =（C 5 H 5）Fe（C 5 H 4）=二茂铁基; p K a '=大约12.8）和1,3-十二碳烯基丙烷-1,3-二酮（十二碳烯基甲烷，5，R = Rc =（C 5 H 5）Ru（C 5 H 4）=钌烯基;

  DOI：

  10.1021/om700609z

文献信息

• Synthesis by ligand exchange and electrochemistry of ruthenocenyl-containing β-diketonato complexes of titanocene. Structure of [TiCp 2 (RcCOCHCOCH 3 )][ClO 4 ]
  作者：Elizabeth Erasmus、Alfred J. Muller、Uwe Siegert、Jannie C. Swarts

  DOI：10.1016/j.jorganchem.2016.05.011

  日期：2016.10

  A new synthetic route involving ligand exchange towards a series of ruthenocenyl-containing β-diketonato titanocene complexes of the type [TiIV(C5H5)2(RcCOCHCOR)][ClO4] with Rc = RuII(C5H5)(C5H4) and R = C10F21 (1), CF3 (2), C6F5 (3), C10H21 (4), CH3 (5), Rc (6) and Fc = FeII(C5H5)(C5H4) (7) are described. The complex [TiIV(C5H5)2(RcCOCHCOCH3)][ClO4], 5, (Z = 4) crystallised in the monoclinic space

  一种新的合成途径，涉及将配体交换为一系列[Ti IV（C 5 H 5）2（RcCOCHCOR）] [ClO 4 ]类型的含钌烯基的β-二酮钛金属茂配合物，其中Rc = Ru II（C 5 H 5）（C 5 H 4）且R = C 10 F 21（1），CF 3（2），C 6 F 5（3），C 10 H 21（4），CH 3（5），描述了Rc（6）和Fc ＝ Fe II（C 5 H 5）（C 5 H 4）（7）。在单斜空间群P2 1 / n中结晶的络合物[Ti IV（C 5 H 5）2（RcCOCHCOCH 3）] [ClO 4 ]，5（Z = 4）结晶。在CH 2 Cl 2 /0.1 M [NBu 4 ] [B（C 6 F 5）4 ]中的循环伏安电化学研究表明，Ti的单电子转移氧化还原过程III / Ti IV和Rc / Rc +对表现出不可逆的电化学行为。在CH 3 CN / 0.1 M [N（n
• Solvent and electrolyte effects in enhancing the identification of intramolecular electronic communication in a multi redox-active diruthenium tetraferrocenoate complex, a triple-sandwiched dicadmium phthalocyanine and a ruthenocene-containing β-diketone
  作者：Henno J. Gericke、Nicola I. Barnard、Elizabeth Erasmus、Jannie C. Swarts、Michael J. Cook、Manuel A.S. Aquino

  DOI：10.1016/j.ica.2010.03.031

  日期：2010.6

  Enhanced electrochemical resolution of anodic processes is possible in the presence of [N(Bu-n)(4)][B(C6F5)(4)], 1, as supporting electrolyte over that obtained in the presence of [N(Bu-n)(4)][PF6]. By changing the anion of the supporting electrolyte to a salt having [B(C6F5)(4)], anions, electrochemical processes of especially cationic analytes can benefit. Thus, the redox chemistry of 0.5 mmol dm(-3) solutions of [Ru-2(mu-FcCOO)(4)center dot(CH3CH2OH)(2)][PF6], 2, Fc = ferrocenyl, in CH2Cl2/[N(Bu-n)(4)][B(C6F5)(4)] were found to involve four well-resolved ferrocenyl- based electrochemical reversible redox processes as well as reduction of Ru-III-Ru-II. At 1.0 mmol dm(-3) concentrations of 2, or in the presence of [N(Bu-n)(4)][PF6], the four ferrocenyl processes coalesced into only two waves as a result of (Fc(+))center dot center dot center dot(PF6-) ion paring. Seventeen of the possible 18 one-electron transfer processes of the biscadmium trisphthalocyaninato complex [Cd-2Pc(C6H13)(8)}(3)], 3, could be observed in THF/[N(Bu-n)(4)][B(C6F5)(4)], but the electrochemical window of CH2Cl2/[N(Bu-n)(4)][B(C6F5)(4)] only allowed detection of 15 of these processes. Although reduction processes were unaffected, THF solvation leading to species such as (3(n+))(THF)(x) with 1 <= n <= 4 and x >= 1 as well as ion pair formation of the type (3n+)center dot center dot center dot(PF6-) prevented good resolution of oxidation processes. The CH2Cl2/[N(Bu-n)(4)][B(C6F5)(4)] system also allowed detection of reversible one- electron transfer ferrocenyl (Fc/Fc(+)) and ruthenocenyl-based (Rc/Rc(+)) processes for both enol and keto isomers of the beta-diketone FcC-OCH(2)CORc, 4, Rc = ruthenocenyl. In CH3CN/[N(Bu-n)(4)][PF6], the ruthenocenyl moiety was oxidised to a Ru-IV species. (C) 2010 Elsevier B.V. All rights reserved.