| 173467-28-2

• CAS: 173467-28-2
• 化学式: C₁₅H₉N₃O₉Ru₃
• 分子量: 678.461
• InChiKey: RLJOJMPTHMBXHY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 Ru3(μ-dppm)(η(1)-Ph2PC.tplbond.CPPh2)(CO)9 以 二氯甲烷 、 乙腈 为溶剂， 以6%的产率得到[Ru3(CO)9((bis(diphenylphosphino)acetylene)Ru3(μ-bis(diphenylphosphino)methane)(CO)9)3]
  参考文献：
  名称：

  Ruthenium cluster chemistry: Monodentate bis(diphenylphosphino)acetylene-ligated cluster modules in chain and dendrimer formation

  摘要：

  Reaction of Ru-3(mu-dppm)(CO)(10) [dppm=bis(diphenylphosphino)methane] with one equivalent of dppa [dppa=bis(diphenylphosphino)acetylene] afforded Ru-3(mu-dppm)(CO)(9)(eta(1)-dppa) which possesses a monodentate dppa ligand, an X-ray structural study revealing that all phosphorus donor atoms are arranged in equatorial coordination sites with respect to the triruthenium cluster plane. Reaction of Ru-3(CO)(9)(NCMe)(3) with excess dppa afforded fair yields of Ru-3(CO)(9)(eta(1)-dppa)(3),which possesses three monodentate dppa ligands. Reaction of three equivalents of Ru-3(mu-dppm)(CO)(9)(eta(1)-dppa) with Ru-3(CO)(9)(NCMe)(3) or reaction of Ru-3(CO)(9)(eta(1)-dppa)(3) with excess Ru-3(mu-dppm)(CO)(10) afforded low yields of the dodecanuclear first-generation dendrimer Ru-3(CO)(9)(PPh2C2PPh2Ru3(mu-dppm)(CO)(9)}(3). Reaction of WIr3(mu-CO)(3)(CO)(8)(eta-C5Me5) with excess Ru-3(mu-dppm)(CO)(9)(eta(1)-dppa) afforded fair yields of the decanuclear dppa-bridged tri-cluster WIr3(CO)(9){PPh2C2PPh2Ru3(mu-dppm)(CO)(9)}(2)(eta-C5Me5). (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.01.027

文献信息

• A High Yield Route to Ruthenaboranes
  作者：Nicholas E. Leadbeater

  DOI：10.1021/om9805537

  日期：1998.12.1

  The versatility and synthetic potential of the novel tris-acetonitrile-substituted cluster Ru3(CO)9(MeCN)3 (3) for the formation of ruthenaboranes in unprecedently high yields are illustrated. Reaction of 3 with [Me4N][B3H8] yields HRu3(CO)9B2H5 (65%) and with BH3·THF yields HRu6B(CO)17 (60%).

  说明了新颖的三乙腈取代簇Ru 3（CO）9（MeCN）3（3）的用途和合成潜力，它们以前所未有的高产率形成了钌硼烷。的反应3与[我4 N] [B 3 ħ 8 ]产生HRU 3（CO）9乙2 ħ 5（65％）中，用BH 3 ·THF产生HRU 6 B（CO）17（60％）。
• W(η2-PhCCPh)3(η1-Ph2PCCPPh2) as a ligand to prepare homo- and hetero-nuclear cluster complexes
  作者：Wen-Yann Yeh、Ching-I Li、Shie-Ming Peng、Gene-Hsiang Lee

  DOI：10.1016/j.jorganchem.2003.09.037

  日期：2004.1

  Reaction of W(eta(2) -PhCequivalent toCPh)(3)(NMe3) (1) and Ph(2)PCequivalent toCPPh(2) (dppa) produces W(eta(2)-PhCequivalent toCPh)(3)(eta(1)-Ph(2)PCequivalent toCPPh(2)) (2), which contains a pendant phosphine group. Treatment of 2 with W(CO)(4)(NCMe)(2) yields [W(eta(2) -PhCequivalent toCPh)(3)](mu, eta(2)-Ph(2)PCequivalent to CPPh2)[W(CO)(4)(NCMe)] (3). Compound 2 reacts with Os-3(CO)(10)(NCMe)(2) to afford Os-3(CO)(10)[(mu, eta(2)-Ph(2)PCequivalent toCPPh(2))W(eta(2)- PhCequivalent toCPh)(3)](2) (4), and reacts with Ru-3(CO)(9)(NCMe)(3) to afford Ru-3(CO)(9)[(mu,eta(2)-PhPCequivalent toCPPh(2))W(eta(2)-PhCequivalent toCPh)(3)](3) (5). The crystal structures of 2 and 3 are determined by an X-ray diffraction study. (C) 2003 Elsevier B.V. All rights reserved.