[(Me4EtC5)ReCl2(μ-S)]2 | 503119-39-9

• 英文名称: [(Me4EtC5)ReCl2(μ-S)]2
• CAS: 503119-39-9
• 化学式: C₂₂H₃₄Cl₄Re₂S₂
• 分子量: 876.87
• InChiKey: VSBKUIMKFFYGHH-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氯仿 、 [(Me4EtC5)ReCl2(μ-S)]2 以 乙醚 、 氯仿 为溶剂， 生成 [(Me4EtC5)ReCl2(μ-S)]2*2CHCl3
  参考文献：
  名称：

  Syntheses of a Cp‘ReS Derivative and More Complex Products

  摘要：

  The reaction of Cp'ReCl2S3 (CP' = Me4EtC5) with slightly less than 2 equiv of a phosphine reagent results in the formation of [Cp'Re(Cl)(2)(mu-S)](2), 2, which has been characterized by an X-ray diffraction study. Reactions of 2 with nucleophiles did not lead to monomeric derivatives of the type Cp'ReS(Cl)(2)(Nuc). The reaction of Cp'ReCl2(SC2H4S) with (Me3Si)(2)S resulted in the formation of three new products: Cp'ReS(SC2H4S), 4; Cp'Re(S-3)(SC2H4S), 5; and a tetranuclear derivative, [(Cp'Re)(2)(mu-S) (mu,eta(2)-SC2H4S)(mu,eta(1)-SC2H4S](2)Cl-2, 6. Complexes 4 and 6 have been characterized by X-ray diffraction studies. The electrochemical properties of the mononuclear Re=S derivative, 4, are compared with those of Re=O and Re=NR analogues.

  DOI：

  10.1021/ic0206241
• 作为产物：
  描述：

  (EtMe4C5)Re(η2-S3)Cl2 在 triphenylphosphine 作用下， 以 乙腈 为溶剂， 以35%的产率得到[(Me4EtC5)ReCl2(μ-S)]2
  参考文献：
  名称：

  Syntheses of a Cp‘ReS Derivative and More Complex Products

  摘要：

  The reaction of Cp'ReCl2S3 (CP' = Me4EtC5) with slightly less than 2 equiv of a phosphine reagent results in the formation of [Cp'Re(Cl)(2)(mu-S)](2), 2, which has been characterized by an X-ray diffraction study. Reactions of 2 with nucleophiles did not lead to monomeric derivatives of the type Cp'ReS(Cl)(2)(Nuc). The reaction of Cp'ReCl2(SC2H4S) with (Me3Si)(2)S resulted in the formation of three new products: Cp'ReS(SC2H4S), 4; Cp'Re(S-3)(SC2H4S), 5; and a tetranuclear derivative, [(Cp'Re)(2)(mu-S) (mu,eta(2)-SC2H4S)(mu,eta(1)-SC2H4S](2)Cl-2, 6. Complexes 4 and 6 have been characterized by X-ray diffraction studies. The electrochemical properties of the mononuclear Re=S derivative, 4, are compared with those of Re=O and Re=NR analogues.

  DOI：

  10.1021/ic0206241