| 152505-32-3

• CAS: 152505-32-3
• 化学式: C₂₂H₃₀FeO₄
• 分子量: 414.325
• InChiKey: YNMMAYLWEYRGPZ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  以 乙腈 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Electrochemical behaviour of tropone diiron pentacarbonyl complexes, Fe2(CO)5[(RC2R)3CO] (R=Me, Et, n-Pr). Formation of a carbon-carbon bond upon reduction

  摘要：

  We herein describe the electrochemical behaviour of some tropone diiron pentacarbonyl complexes Fe2(CO)5[(RC2R)3CO] (R=Et, Me, n-Pr). All these compounds exhibit a cyclic voltammetric (CV) response consisting of an electrochemically and chemically reversible one-electron reduction process at moderate cathodic potentials and a totally irreversible further reduction at c. -2 V versus SCE. At-root temperature (in the long electrolysis time scale) the electrogenerated monoanion Fe2(CO)5[(RC2R)3CO]- smoothly but completely decomposes to Fe(CO)3[(RC2R)3CO]. In this process the organic chain rearranges, and a new C-C bond is formed.

  DOI：

  10.1016/s0020-1693(00)92338-7