([Ag(4,4'-azobis(pyridine)]PF6)n | 854589-11-0

• 英文名称: ([Ag(4,4'-azobis(pyridine)]PF6)n
• CAS: 854589-11-0
• 化学式: Ag*C₁₀H₈N₄*F₆P
• 分子量: 437.033
• InChiKey: LIPLFEWDVAXGHH-QDBORUFSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸银 、 (E)-1,2-Di(pyridin-4-yl)diazene 以 乙醇 、 水 为溶剂， 以96%的产率得到([Ag(4,4'-azobis(pyridine)]PF6)n
  参考文献：
  名称：

  Synthesis and Crystallographic Characterization of Low-Dimensional and Porous Coordination Compounds Capable of Supramolecular Aromatic Interaction Using the 4,4‘-Azobis(pyridine) Ligand

  摘要：

  Coordination compounds with a 4,4'-azobis(pyridine) (azpy) ligand, {[M-2(azpy)(6)(H2O)(5)](.)4PF(6)(.)azpy-H2O}(n) (M = Ni-II, (1) or Co-II (2)) (0-dimensional (0-D) dimer), {[Zn(azpy)(3)(H2O)(2)](.)2PF(6)(.)2azpy-4H(2)O}(n) (3) (1-dimensional (1-D) fishbone-type chain), {[Ag(azpy)](PF6)-P-.}(4) (1-D linear chain), {[Mn(NCS)(2)(azpy)(2)](.)azpy}, (5) (2-dimensional (2-D) grid sheet), and {[Ni(NCS)(2)(azpy)(2)](.)3toluene}, (6) (2-D grid sheet), were synthesized and structurally characterized. Compounds 1 and 2 have a 0-D dimer motif, in which one M-II (M-II = N-II or Co-II) coordination site is shared by unidentate azpy and H2O ligands, each with half-occupancy, i.e., exhibiting static disorder. Compounds 3 and 4 afford 1-D fishbone-type and 1-D linear chain motifs, respectively. Azpy mediates pi-pi and pi-p interactions between these low-dimensional structures. Compounds 5 and 6 possess a 2-D grid sheet motif. These sheets assemble to form microporous frameworks that incorporate aromatic guests, such as coordination-free azpy (5) and toluene (6), There exist not only pi-pi and pi-p interactions but also CH-pi interactions between the framework azpy ligands and guests. It should be noted that the azpy ligand is a good candidate for the construction of new assembling systems of coordination compounds through its aromatic interactions.

  DOI：

  10.1021/ic048371u