cis-[Pd(C6F5)2(benzyldimethylamine)(CO)] | 160491-11-2

• 英文名称: cis-[Pd(C6F5)2(benzyldimethylamine)(CO)]
• CAS: 160491-11-2
• 化学式: C₂₂H₁₃F₁₀NOPd
• 分子量: 603.755
• InChiKey: ZJXWQYUIGGNYTC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  cis-[Pd(C6F5)2(benzyldimethylamine-κC(1),,kappa.N)] 在 CO 作用下， 以 二氯甲烷 为溶剂， 以48%的产率得到cis-[Pd(C6F5)2(benzyldimethylamine)(CO)]
  参考文献：
  名称：

  Synthesis, molecular structure and reactivity of cis-[Pd(C₆F₅)₂(C₆H₅CH₂NMe₂-κC¹, κN)] a compound displaying an unusual η¹arene–palladium interaction

  摘要：

  The reaction between cis-[Pd(C6F5)2(thf)2] (thf = tetrahydrofuran) and benzyldimethylamine rendered cis-[Pd(C6F5)2(C6H5CH2NMe2-kappaC1,kappaN)] 1, a four-co-ordinate compound containing an unusual eta1 arene-palladium interaction with the benzyldimethylamine acting as a bidentate chelating ligand. Complex 1 reacts with acetone, acetonitrile, dimethyl sulfoxide or CO (L) to yield cis-[Pd(C6F5)2(NMe2CH2C6H5)(L)] 2-5 respectively, which do not have a eta1 arene-palladium interaction. The reaction of 1 with Br- or SPMe2Ph (L') (molar ratio 1:1) produced the complete displacement of the amine and the formation of [(F5C6)2Pd(mu-L')2Pd(C6F5)2]n- (n = 2 or 0), and with Cl- (molar ratio 1:1) a mixture of complexes is formed. The crystal structures of compounds 1 and 2 have been determined.

  DOI：

  10.1039/dt9940003143