| 503536-57-0

• CAS: 503536-57-0
• 化学式: C₇H₈*C₈₀H₇₆Co₄N₁₀O₉
• 分子量: 1649.66
• InChiKey: KMBJSJKRCDOSKG-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1H-吡咯-2,5-二甲醛 、 邻氨基二苯胺 在 [Co(OH)n(OOCC(CH₃)3)(2-n)]x n=0.05-0.1 作用下， 以 乙腈 为溶剂， 以58%的产率得到
  参考文献：
  名称：

  摘要：

  The reactions of pyrrole-2,5-dicarbaldehyde (1) with 2-aminodiphenylamine (3) taken in a ratio of 1 : 2 in the presence of polinuclear nickel(II) and cobalt(II) trimethyl-acetate complexes were studied in MeCN. The reaction with Ni-9(HOOCCMe3)(4)(mu(4)-OH)(3)(mu(3)-OH)(3)(OOCCMe3)(12) (2) afforded the mononuclear complex Ni(OOCCMe3)(2)[(PhHN)C6H4NHCHC4H2NCHNC6H4(NHPh)] (4) with a new ligand, which is the product of condensation of one molecule 1 with two molecules 3 and contains two NHPh groups. By contrast, the reaction with the polymeric complex [Co(OH)n(OOCCMe3)(2-n)](x), (5, n = 0.05-0.1) gave rise to the tetranuclear complex Co-4(mu(4)-O)(mu-OOCCMe3)(4)L-2 (6), where L is, apparently, the product of further oxidation of Schiff's base to the benzimidazole derivative. The structures of compounds 4 and 6 were established by X-ray diffraction analysis.

  DOI：

  10.1023/a:1020995930577