| 157741-82-7

• CAS: 157741-82-7
• 化学式: C₃₇H₂₆O₈Os₃W
• 分子量: 1353.06
• InChiKey: RNJGGZQGFRQYCT-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  以 氯仿 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  Consecutive C-C Bond Scission of an Allyl Ligand on a WOs3 Cluster Framework

  摘要：

  The reaction, of Os-3(CO)(9)(C(2)R(2)) (R = Tol, Ph; Tol = p-C(6)H(4)Me) with Cp(CO)(2)W=CTol (Cp = eta(5)-C5H5) produces an alkylidyne-alkyne complex CpWOs(3)(CO)(10)(mu(3)-eta(2)-C(2)R(2))(mu(3)-CTol) [1a (R = Tol), 1b (R = Ph)], which is converted to two isomeric allyl complexes CpWOs(3)(CO)(10)(mu(3)-C(3)R(2)Tol) (2a,b and 3a,b) upon thermolysis. Complexes 3a,b, in which the allyl ligand is pi-coordinated to the tungsten atom, undergo consecutive allyl C-C bond cleavage to afford trialkylidyne complexes CpWOs(3)(CO)(9)(mu(3)-CR)(2)(mu 3-CTol) (5a,b) via alkylidyne-alkyne complex CpWOs(3)(CO)(10)(mu(3)-eta(2)-C(2)R(2))(mu(3)-CTol) or CpWOs(3)(Co)(10)(mu 3-eta(2)-C(2)RTol)(mu(3)-CR) (4a,b), together with formation of CpWOs(3)(CO)(8)(mu(3)-perpendicular to-C(2)R(2))(mu(3)-CTol) or CpWOs(3)(CO)(8)(mu(3)-eta(2)-perpendicular to-C(2)RTol)(mu(3)-CR) (6a,b) as a minor product.

  DOI：

  10.1021/om00021a004