Organometallics in Water: Three-Coordinate [Pt0(N,N-chelate)(η2-olefin)] Complexes Containing New Chiral Ligands Based on α-d-Mannose
摘要:
New bidentate nitrogen ligands based on alpha-D-mannose were prepared and investigated by preparing a family of platinum(O) complexes of formula [Pt(N,N-chelate)(eta(2)-olefin)]. The ability of one N,N-chelate to induce a stereoselective reaction in water was assessed.