[Fe(η5-C5H4-1-C5H4N)2][Fe(η5-C5H4COOH)2] | 625450-77-3

• 英文名称: [Fe(η5-C5H4-1-C5H4N)2][Fe(η5-C5H4COOH)2]
• CAS: 625450-77-3
• 化学式: C₁₂H₁₀FeO₄*C₂₀H₁₆FeN₂
• 分子量: 614.263
• InChiKey: YBRVNKWYWJTITQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,1'-bisferrocenedicarboxylic acid 、 1,1'-bis(4-pyridinyl)ferrocene 以 甲醇 为溶剂， 生成 [Fe(η5-C5H4-1-C5H4N)2][Fe(η5-C5H4COOH)2]
  参考文献：
  名称：

  Design, Synthesis, and Structural Characterization of Molecular and Supramolecular Heterobimetallic Metallamacrocycles Based on the 1,1‘-Bis(4-pyridyl)ferrocene (Fe(η⁵-C₅H₄-1-C₅H₄N)₂) Ligand

  摘要：

  The bidentate ferrocenyl sandwich [Fe(eta(5)-C5H4-1-C5H4N)(2)] (1) has been used as a coordination ligand in reactions with AgNO3, Cd(NO3)(2), Cu(CH3COO)(2), Zn(CH3COO)(2), and ZnCl2 to obtain the heterobimetallic metallamacrocyclic derivatives [Fe(eta(5)-C5H4-1-C5H4N)(2)](2)Ag-2(NO3)(2).1.5H(2)O, [Fe(eta(5)-C5H4-1-C5H4N)(2)](2) Cu-2(CH3COO)(4).3H(2)O, [Fe(eta(5)-C5H4-1-C5H4N)(2)](2)Cd-2(NO3)(4).CH3OH.0.5C(6)H(6), [Fe(eta(5)-C5H4-1-C5H4N)(2)](2)Zn-2(CH3COO)(4), and [Fe(eta(5)-C5H4-1-C5H4N)(2)](2)Zn2Cl4 (abbreviated in the following as (1Ag(I))(2)(2+), (1Cd(II))(2)(4+), (1Cu(II))(2)(4+), (1Zn(acetate)(II))(2)(4+), and (1Zn(chloride)(II))(2)(4+)). The reaction with the ferrocenedicarboxylic acid complex [Fe(eta(5)-C5H4COOH)(2)] has led to the supramolecular adduct [Fe(eta(5)-C5H4-1-C5H4N)(2)] [Fe(eta(5)-C5H4COOH)(2)] (1[Fe(eta(5)-C5H4COOH)(2)]). All compounds have been structurally characterized by single-crystal X-ray diffraction.

  DOI：

  10.1021/om030432t