NaSn2(O(i-Pr))9 | 860009-88-7

• 英文名称: NaSn2(O(i-Pr))9
• 英文别名: NaSn2(isopropoxide)9
• CAS: 860009-88-7
• 化学式: C₂₇H₆₃O₉Sn₂*Na
• 分子量: 792.202
• InChiKey: JKYAAKGNIXZBLN-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  trichlorotritetrahydrofuran chromium(III) 、 NaSn2(O(i-Pr))9 以 苯 为溶剂， 以94%的产率得到dichlorochromium(1+);propan-2-olate;tetra(propan-2-yloxy)stannane
  参考文献：
  名称：

  Synthesis and Physico‐Chemical Studies of New Types of Heteroleptic Isopropoxometallates of Chromium(III)

  摘要：

  Novel heterobimetallic isopropoxides of chromium(III) of the types: {CrCl2[Al(OPr-i)(4)](THF)(2)} (1a), {CrCl[Al(OPr-i)(4)](2)(THF)} (1b), {CrCl-[Ga(OPr-i)(4)](2)(THF)} (1c), {CrCl[Al(OPr-i)(6)](2)(THF)} (1d), {CrCl2-[Zr-2(OPr-i)(9)]} (1e), {CrCl2[Sn-2(OPr-i)(9)]) (1f), and {CrCl[Zr-2(OPr-i)(9)](2)} (1g) have been prepared by the reactions of CrCl3.3THF in the required molar ratios with a variety of potassium alkoxometallates in tetrahydrofuran (THF) or benzene. Heteropenta-and hexanuclear complexes, (Cr[Zr-2(OPr-i)(9)](2)[Al(OPr-i)(4)]} (2) and {Cr[Zr-2(OPr-i)(9)](2)[Al(OPr-i)(4)]} (3), were obtained by the interactions of a chloro(isopropoxometallato)chromium(III) complex with an appropriate potassium isopropoxometallate in the desired molar ratios in benzene. Elemental analyses and molecular weight measurements of these interesting coordination compounds are consistent with the formulations depicted above. Electronic spectroscopic and magnetic susceptibility data support an octahedral environment around chromium(III).

  DOI：

  10.1081/sim-120021645

文献信息

• Agrawal, Neetu; Singh, Anirudh, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2007, vol. 46, # 12, p. 1938 - 1946
  作者：Agrawal, Neetu、Singh, Anirudh

  DOI：——

  日期：——