[Cu2(3-acetylcoumarin-N(4)-phenylthiosemicarbazone(-H))2Cl2(H2O)2] | 1161916-00-2

• 英文名称: [Cu2(3-acetylcoumarin-N(4)-phenylthiosemicarbazone(-H))2Cl2(H2O)2]
• CAS: 1161916-00-2
• 化学式: C₃₆H₃₂Cl₂Cu₂N₆O₆S₂
• 分子量: 906.817
• InChiKey: UJOYOXNLAPIVLV-YYTDKVDJSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 3-acetylcoumarin-N(4)-phenylthiosemicarbazone 、 水 以 甲醇 、 乙醇 、 水 为溶剂， 以76%的产率得到[Cu2(3-acetylcoumarin-N(4)-phenylthiosemicarbazone(-H))2Cl2(H2O)2]
  参考文献：
  名称：

  Synthesis and characterisation of new Schiff base metal complexes and their use as catalysts for olefin cyclopropanation

  摘要：

  New transition metal complexes of Co-II, Cu-II, Ni-II and (VO)-O-IV with the Schiff base, HL, 3-acetylcoumarin-N(4)-phenylthiosemicarbazone have been prepared. Characterisation of the HL ligand and its complexes is also reported. Mass spectra and NMR assignments for the ligand, using COSY, NOESY homonuclear and HMQC and HMBC heteronuclear correlation techniques were carried out. Electronic and magnetic moments of the complexes indicate that the geometries of the metal centres are either distorted octahedral, square pyramidal, square planar or tetrahedral. The structures are consistent with the IR, UV-Vis, ESR, as well as conductivity and magnetic moments measurements. Cyclopropanation reactions of unactivated olefins by ethyldiazoacetate (EDA) in the presence of (LCuCl)-Cl-II as catalyst proceed with excellent TON (up to 9625). (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.09.012