Synthesis and reactivity of a novel unsaturated dimanganese hydride complex, [Mn2H2(CO)6{(OEt)2POP(OEt)2}]. X-Ray Structure of [Mn4Cu2H6(CO)12{(OEt)2-POP(OEt)2}2]
作者:Victor Riera、Miguel A. Ruiz、Antonio Tiripicchio、Marisa Tiripicchio Camellini
DOI:10.1039/c39850001505
日期:——
The synthesis of [Mn2H2(CO)6(OEt)2POP(OEt)2}] and its reactions with tetrahydrothiophene, methyl-triphenylphosphinegold(I), sodium amalgam followed by triphenylphosphine–group 1b metal cations, and with copper(I) haliders are described; the structure of [Mn4Cu2H6(CO)12(OEt)2-POP(OEt)2}2] has been established by X-ray diffraction.
[Mn 2 H 2(CO)6 (OEt)2 POP(OEt)2 }]的合成及其与四氢噻吩,甲基三苯基膦金(I),钠汞齐,然后三苯基膦基团1b的金属阳离子以及与描述了铜(I)卤化物;通过X射线衍射确定了[Mn 4 Cu 2 H 6(CO)12 (OEt)2- POP(OEt)2 } 2 ]的结构。