trans-[bis-2,6-(2-benzimidazolyl-κN(2))-pyridine-κN]nitrobis(triphenylphosphine-P)ruthenium(II) perchlorate ethanol solvate | 198138-08-8

• 英文名称: trans-[bis-2,6-(2-benzimidazolyl-κN(2))-pyridine-κN]nitrobis(triphenylphosphine-P)ruthenium(II) perchlorate ethanol solvate
• CAS: 198138-08-8
• 化学式: C₂H₆O*C₅₅H₄₃N₆O₂P₂Ru*ClO₄
• 分子量: 1128.52
• InChiKey: YOGYSBZHBLHFTG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  trans-[RuCl(PPh3)2(C5H3N(C6H4CHN2)2)]ClO4 、 sodium nitrite 以 not given 为溶剂， 生成 trans-[bis-2,6-(2-benzimidazolyl-κN(2))-pyridine-κN]nitrobis(triphenylphosphine-P)ruthenium(II) perchlorate ethanol solvate
  参考文献：
  名称：

  trans-[Bis-2,6-(2-benzimidazolyl-κN²)pyridine-κN]nitrobis(triphenylphosphine-P)ruthenium(II) Perchlorate Ethanol Solvate

  摘要：

  In the title compound, [Ru(NO2)(C19H13N5)(C18H15P)(2)]ClO4.C2H6O, the two phosphine ligands are in trans positions. The Ru atom and imidazolylpyridine moiety are almost coplanar, with the fused ring of the imidazolyl groups somewhat bent from the plane due to the steric hindrance of the phosphine phenyl groups. The nitro ligand is coordinated so that the NO2 group is rotated 40.5(1)degrees from the imidazolylpyridine plane.

  DOI：

  10.1107/s0108270197006082