| 1051971-11-9

• CAS: 1051971-11-9
• 化学式: ClH₁₅N₅Ru*Cl₆Pt
• 分子量: 629.474
• InChiKey: LHAUWSSQJQHPQA-UHFFFAOYSA-G

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent, solid phase) 为溶剂， 生成 ruthenium platinum
  参考文献：
  名称：

  Synthesis, properties, and thermal decomposition products of [Ru(NH3)5Cl][PtCl6] and [Ru(NH3)5Cl]2[PtCl6]Cl2

  摘要：

  The double complex salts [Ru(NH3)(5)Cl][PtCl6] (I) and [Ru(NH3)(5)Cl](2)[PtCl6]Cl-2 (II) were synthesized and studied by X-ray diffraction. They were found to be isostructural to the previously synthesized [Rh(NH3)(5)Cl][OsCl6] and [Ir(NH3)(5)Cl](2)[PtCl6]Cl-2. The thermolysis of the complexes in the atmosphere of hydrogen and helium was studied by the powder X-ray diffraction analysis. The product of the salt I thermolysis is a single-phase solid solution Ru0.5Pt0.5 (a = 3.857(3) angstrom), the thermolysis of salt II results in a double-phase metallic powder.

  DOI：

  10.1134/s1070328407070093
• 作为产物：
  描述：

  ammonium hexachloroplatinate 、 pentaamminechlororuthenium(III) dichloride 以 水 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Synthesis, properties, and thermal decomposition products of [Ru(NH3)5Cl][PtCl6] and [Ru(NH3)5Cl]2[PtCl6]Cl2

  摘要：

  The double complex salts [Ru(NH3)(5)Cl][PtCl6] (I) and [Ru(NH3)(5)Cl](2)[PtCl6]Cl-2 (II) were synthesized and studied by X-ray diffraction. They were found to be isostructural to the previously synthesized [Rh(NH3)(5)Cl][OsCl6] and [Ir(NH3)(5)Cl](2)[PtCl6]Cl-2. The thermolysis of the complexes in the atmosphere of hydrogen and helium was studied by the powder X-ray diffraction analysis. The product of the salt I thermolysis is a single-phase solid solution Ru0.5Pt0.5 (a = 3.857(3) angstrom), the thermolysis of salt II results in a double-phase metallic powder.

  DOI：

  10.1134/s1070328407070093