trans-dichloro(5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)cobalt(III) chloride | 147859-14-1

• 英文名称: trans-dichloro(5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)cobalt(III) chloride
• CAS: 147859-14-1
• 化学式: C₁₆H₃₂Cl₂CoN₄*Cl
• 分子量: 445.809
• InChiKey: FWLPQMLELPKBBV-PRNSBOFBSA-K

反应信息

• 作为反应物：
  描述：

  trans-dichloro(5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)cobalt(III) chloride 、 sodium thiocyanide 以 盐酸 为溶剂， 生成 trans-(5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene-N,N',N'',N''')di(isothiocyanato-N)cobalt(III) thiocyanate
  参考文献：
  名称：

  trans-(5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene-N,N',N'',N''')di(isothiocyanato-N)cobalt(III) Thiocyanate

  摘要：

  The Co-III ion in the title compound, [CO(NCS)(2)(C16H32-N-4)](SCN), is six-coordinate in a distorted octahedral environment, with the four N atoms of the macrocyclic tetradentate ligand equatorial and the N atoms of two isothiocyanato groups axial. The tetradentate macrocyclic ligand is in a planar conformation, with the two five-membered rings in gauche conformations and the two six-membered rings in twist conformations. The complex has an RR or SS configuration for the two chiral amine N centres. Intermolecular hydrogen bonds between the two NH groups and the unbonded thiocyanate anion help stabilize the crystal structure.

  DOI：

  10.1107/s0108270196008724