Single-crystal N(CH3)(4)N(C2H5)(4)CoBr4 was grown from an aqueous solution by a slow evaporation method, and dielectric properties were measured over the temperature range from -190 degrees C to 50 degrees C. Four phases, phase I (T > -164 degrees C), phase II (-164 degrees C > T > -172 degrees C), phase III (-172 degrees C > T > -179 degrees C) and phase IV (-179 degrees C > T) were recognized and we found that phase II and phase III are ferroelectric and antiferroelectric phases, respectively.