| 115332-15-5

• CAS: 115332-15-5
• 化学式: C₂₄H₂₆Mn₂N₄O₇
• 分子量: 592.369
• InChiKey: SECKLAYPICFPCB-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  在 乙酸盐 作用下， 以 水 为溶剂， 以<1的产率得到
  参考文献：
  名称：

  Formation of a high valent di-μ-oxo manganese dimer in aqueous solution

  摘要：

  We find an unusual example in which different clusters can be isolated from the same reaction mixture depending on the choice of counter-ion. The complex [(bipy)2Mn(III)(mu-O)2Mn(IV)(bipy)2]3+ (1) (bipy = 2,2'-dipyridyl) is isolated from Mn(II) and permanganate in acetate buffer with ClO4-, but [(bipy)(H2O)Mn(III)(mu-O)(mu-OAc)2Mn(III)(bipy)(H2O)]2+ (2) with NO3-.1e-/2H+ or 1e-/1H+ proton-coupled electron transfer chemistry is found for 2 according to the type of buffer used.. The new complex [(bipy)(H2O)Mn(III)(mu-O)2(mu-OAc)Mn(IV)(bipy)(H2O)]2+ (3) is also postulated as an intermediate in the formation of 1.

  DOI：

  10.1016/s0020-1693(00)92318-1