meso-tetrakis(3,5-di-t-butylphenyl)porphyrin-iridium(III) carbonyl chloride | 145780-17-2

• 英文名称: meso-tetrakis(3,5-di-t-butylphenyl)porphyrin-iridium(III) carbonyl chloride
• CAS: 145780-17-2
• 化学式: C₇₇H₉₂ClIrN₄O
• 分子量: 1317.28
• InChiKey: ZCEDYTUZMOYYFU-SCLQQTPKSA-M

反应信息

• 作为产物：
  描述：

  5,10,15,20-tetrakis-(3,5-di-tert-butylphenyl)porphyrin 、 bis(1,5-cyclooctadiene)diiridium(I) dichloride 以 xylene 为溶剂， 以52%的产率得到meso-tetrakis(3,5-di-t-butylphenyl)porphyrin-iridium(III) carbonyl chloride
  参考文献：
  名称：

  A sterically hindered and highly lipophilic metalloporphyrin: Crystal and molecular structure of meso-tetrakis(3,5-di-t-butylphenyl)porphyrin-iridium(III) carbonyl chloride

  摘要：

  The title complex was synthesized and characterized by single-crystal X-ray analysis. The iridium(III) atom is coordinated by four nitrogen atoms in a square-planar fashion with Ir-N = 2.04(1) angstrom, and the coordination sphere is completed by chloro and carbonyl ligands at the axial positions with Ir-Cl = 2.293(6), Ir-C = 1.95(2) angstrom and Cl-Ir-C = 172.7(6)-degrees. The porphyrin ring is nearly planar with the dihedral angle between adjacent pyrrole rings at only 1.2-degrees. The dihedral angles between the porphyrin ring and the phenyl rings lie in the range 68.3-81.8-degrees.

  DOI：

  10.1016/s0277-5387(00)80242-9