Fe2(CO)6(.mu-SeCH2Te) | 162829-84-7

• 英文名称: Fe2(CO)6(.mu-SeCH2Te)
• CAS: 162829-84-7
• 化学式: C₇H₂Fe₂O₆SeTe
• 分子量: 500.343
• InChiKey: OHPKESJUQRXZLZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  重氮甲烷 、 Fe2(CO)6(μ-SeTe)2 以 乙醚 为溶剂， 以4%的产率得到Fe2(CO)6(.mu-SeCH2Te)
  参考文献：
  名称：

  Synthesis and characterisation of the methylene-inserted mixed-chalcogenide compounds Fe2(CO)6(μ-SeCH2Te) and Fe2(CO)6(μ-SCH2Te)

  摘要：

  The methylene-bridged, mixed-chalcogen compounds Fe-2(CO)(6)(mu-SeCH2Te) (1) and Fe-2(CO)(6)(mu-SCH2Te) (3) have been synthesised from the room temperature reaction of diazomethane with Fe2(CO)6(mu-SeTe) and Fe-2(CO)(6)(mu-STe), respectively. Compounds 1 and 3 have been characterised by IR, H-1, C-13, Se-77 and (125)=Te NMR spectroscopy. The structure of 1 has been elucidated by X-ray crystallography. The crystals are monoclinic, space group P2(1)/n, a = 6.695(2), b = 13.993(5), c = 14.007(4) Angstrom, beta = 103.03(2)degrees, V = 1278(7) Angstrom 3, Z = 4, D-c = 2.599 g cm(-3) and R = 0.030 (R(w) = 0.047).

  DOI：

  10.1016/0022-328x(94)05165-8