Cp(*)(dmpe)Mo(H)Si(C12H8) | 1182280-33-6

• 英文名称: Cp(*)(dmpe)Mo(H)Si(C12H8)
• CAS: 1182280-33-6
• 化学式: C₂₈H₄₀MoP₂Si
• 分子量: 562.599
• InChiKey: QCTVMGWFYWORHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  5H-dibenzo[b,d]silole 、 (η5-1,2,3,4,5-pentamethylcyclopentadienyl)(1,2-bis(dimethylphosphino)ethane)(η3-benzyl)molybdenum 以 苯 为溶剂， 以54%的产率得到Cp(*)(dmpe)Mo(H)Si(C12H8)
  参考文献：
  名称：

  Germylene and Silylene Complexes of Molybdenum via E−H (E = Ge, Si) Bond Activations: Steric Influences on Intramolecular MoH···E Interactions

  摘要：

  Reactions of Cp*(dmpe)Mo(eta(3)-CH2Ph) with organogermanes (RR'GeH2) afforded germylene complexes Cp*(dmpe)Mo-(H)GeRR' (RR' = Ph-2 (2), Et-2 (3), (Mes)H (4), (Bu-t)H (5)). Compound 2 does not possess an intramolecular H center dot center dot center dot Ge interaction of the type exhibited by its silicon analogue and by 3. The existence of such interactions appears to depend on the steric properties of substituents on the Ge (or Si) atom. For comparison a silylene complex was prepared by reaction of 9-silafluorene with 1, to give Cp*(dmpe)Mo(H)Si(C12H8), which on the basis of NMR spectroscopy does not possess a significant Si center dot center dot center dot H interaction.

  DOI：

  10.1021/ic901168s