Ru2(CO)6[4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione(μP-P)] | 169696-20-2

• 英文名称: Ru2(CO)6[4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione(μP-P)]
• CAS: 169696-20-2
• 化学式: C₃₅H₂₂O₈P₂Ru₂
• 分子量: 834.642
• InChiKey: USLXDTAPFVWMOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Ru2(CO)6[4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione(μP-P)] 以 二氯甲烷 为溶剂， 以68%的产率得到Ru2(CO)6(μ2-PPh2)[μ-η(1),η(1)-C=C(PPh2)C(O)CH2C(O)]
  参考文献：
  名称：

  Shen, Huafeng; Bott, Simon G.; Richmond, Michael G., Organometallics, 1995, vol. 14, # 10, p. 4625 - 4634

  摘要：

  DOI：
• 作为产物：
  描述：

  十二羰基三钌 、 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione 以 甲苯 为溶剂， 以60%的产率得到Ru2(CO)6[4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione(μP-P)]
  参考文献：
  名称：

  Shen, Huafeng; Bott, Simon G.; Richmond, Michael G., Organometallics, 1995, vol. 14, # 10, p. 4625 - 4634

  摘要：

  DOI：

文献信息

• Photochemically mediated alkyne metalation in the donor–acceptor complexes Ru2(CO)6(μ-P-P) [where P-P=bpcd, (Z)-Ph2PCH=CHPPh2]. X-ray diffraction structure of the zwitterionic compound Ru2(CO)6[μ-(Z)-MeO2CC=CCO2Me](μ-bpcd)
  作者：Simon G. Bott、Huafeng Shen、Michael G. Richmond

  DOI：10.1016/s0020-1693(99)00417-x

  日期：2000.4

  Near-Uv irradiation of the donor-acceptor complexes Ru-2(CO)(6)(mu-bpcd) and Ru-2(CO)(6)[mu-(Z)-Ph2PCH=CHPPh2] in the presence of dimethyl acetylenedicarboxylate (dmad) gives the dimetalated alkene complexes Ru-2(CO)(6)[mu-(Z)-MeO2CC=CCO2Me](mu-diphosphine). Each new alkene complex was characterized in solution and by X-ray diffraction analysis in the case of the bpcd-substituted derivative. The X-ray structure of Ru-2(CO)(6)[mu-(Z)-MeO2CC=CCO2Me](mu-bpcd) confirms the formal oxidative addition of the dmad ligand across the dative Ru-Ru bond. (C) 2000 Elsevier Science S.A. All rights reserved.