| 193612-43-0

• CAS: 193612-43-0
• 化学式: Cl₂Cu
• 分子量: 137.0
• InChiKey: ORTQZVOHEJQUHG-UIZOZEHHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.38
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  铜 、 chlorine 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Study of isotope effects in the ground state of the symmetrical isotopomers of CuCl2

  摘要：

  Investigations of the ground state of CuCl2 have been pursued, recording laser induced fluorescence spectra on a Bomem DA3 Fourier transform spectrometer in the range 10000-16500 cm(-1). A single mode ring dye laser, set in the red (615-665 nm), excited the (IIu)-I-2-(X) over tilde(2)II(g) electronic transition in copper dichloride vapour. Analysis of spectra recorded from isotopically enriched samples of CuCl2 allowed us to check our assignment of vibrational stretching quantum numbers nu(1)(less than or equal to 7) and nu(3)(less than or equal to 8) in the ground state. A normal mode model including isotope effects has been used to fit data from all four symmetrical isotopomers of copper dichloride. The rms deviation of the fit containing about 4000 lines is 0.040 cm(-1). From this model, we find an equilibrium Cu-Cl bond length of 0.203335(5) nm and force constant k(1) =277.28(1) N m(-1).

  DOI：

  10.1016/0301-0104(93)85088-p